“…In the HMBC spectrum of 2, prominent crosspeaks from H-17 2b/ to C-13 2 and C-17 3 and H-17 2b to C-17 3 were observed. These observations revealed that C-13 2 and C-17 3 are within a three bond proximity to H-17 2b and H-17 2b '. Thus 2, name chlorophyllonelactone a, has a structure in which ring V of 1 has been converted to a δ-lactone (17,18 Concentration: *, 1 mg/0.6 ml; **, 0.6 mg/0.6 ml.…”