“…The Pb isotope ratio can be used to identify the sources and transport pathways of Pb in pollution studies (Hu et al, 2015). Previous works have shows that the use of lead isotopes is a good tool in order to know the origin of Pb and to identify the types of Pb according to anthropogenic or geogenic origin (Ettler et al, 2004;Li et al, 2011;Álvarez-Iglesias et al, 2012); this is because the Pb emitted into the atmosphere maintains a characteristic isotopic composition (signature) and does not change during the physical/ physicochemical processes associated with smelting, refining or manufacturing (Flegal and Smith, 1995 Pb from wines and soil of origin (Avram et al, 2014;Kristensen et al, 2016;Dehelean and Voica, 2012;Almeida et al, 2016), this representing the starting premise for geographical origin determination. The lead isotope ratio depends on factors such as thorium and uranium content in the soil, weathering processes and original rock age, which provide a fingerprint used for different forensic and archeological purposes (Komárek et al, 2008;Roux et al, 2004;Dreyfus et al, 2007).…”