In order to reveal the formation mechanism of hydrochemical characteristics in Tongchuan CityThere is an exchange between the Ca 2+ in water and Na + in soil, which leads to γNa>γCl. As the exchange time in deep water is longer than that of shallow water, the exchange and adsorption of ions are more sufficient. The value of γNa/(γNa+γCl) demonstrates that with increasing of ground water depth, the level of cation exchange enhances, which leads to the dominant cation turning to Ca 2+ from Na + . The value of γHCO 3 +γSO 4 /γCa+γMg demonstrates the shallow water is mainly from atmospheric rainfall and the influence of cation exchange is more obvious on deep water. The types of shallow water in Tongchuan City are mainly HCO 3 ·SO 4 -Ca. Its classification is relatively complex. Whereas, the deep water is mainly HCO 3 -Na and the category of underground water is simple. As for shallow water, the content of alkaline earth metal is larger than that of alkali metal. For the deep water, the content of weak acid group is larger than that of strong acid group. In the region of upper reaches, the features of both shallow and deep waters are mainly weak acid and alkaline earth metal. The chemical composition mainly consists of carbonate leaching. With the flowing of underground water, the shallow water turns to be strong acid and alkaline earth metal and the deep water turns to be weak acid and alkali metal.