A surge in global demand for rare metals, mainly for uses in high-tech electronic devices and low-carbon energy production, has intensified exploration for these strategically important commodities. Pegmatites in the Ijio granites, south-west Nigeria, are known to contain tin-niobium-tantalum-zinc mineralisation and gem pockets which until recently have been little studied. The granites and pegmatites were emplaced into gneisses and metasediments of the Pan-African Basement Complex at ca 600 Ma (Grant, 1970). They are texturally diverse, ranging from fine-grained, to medium grained biotite granites, porphyritic granites and granodiorites. They generally contain perthitic microcline as well as biotite and muscovite and lesser amounts of hornblende, apatite, monazite, tourmaline, garnet, rutile and magnetite.From major and trace element studies, the granites are metaluminous to peraluminous, and calc-alkaline to alkaline. They are moderately to highly enriched in Li (18 to 93 ppm), Be (12 to 243 ppm), Rb (24 to 369 ppm), Cs (5 to 33 ppm), Nb (4 to 37 ppm), but they generally contain low Ta (2 to 6 ppm). Total REE abundances range from 63 to 300 ppm, and La/YbN from 6?59 to 32?21. Their REE patterns are highly enriched in the LREE but are relatively depleted in HREE, and they have moderate to strongly negative Eu anomalies. They also generally have low Yb (,2 ppm) and relatively high Sr (.400 ppm). From these characteristics the granites are likely to be relatively evolved, which is supported by high average ratios for K/Cs53746; K/Rb5310; Rb/ Cs512 and Nb/Ta53.The mineralogy and geochemistry of the granites is similar to granites in the Precambrian basement complex of south-west Nigeria. However, their petrographic and chemical variations, and the production of pegmatites, are inferred to have resulted from extreme fractional crystallisation. Studies of the mineral chemistry of the granites, and their relations to the pegmatites, are ongoing, which is essential in the development of exploration models for different rare metal mineralisation in the Ijio granites, particularly for Li, Ta, Nb and Sn.