Isotope engineering achieved by local coordination design in Ti-Pd co-doped ZrCo-based alloys
Jiacheng Qi,
Xu Huang,
Xuezhang Xiao
et al.
Abstract:Deuterium/Tritium (D/T) handling in defined proportions are pivotal to maintain steady-state operation for fusion reactors. However, the hydrogen isotope effect in metal-hydrogen systems always disturbs precise D/T ratio control. Here, we reveal the dominance of kinetic isotope effect during desorption. To reconcile the thermodynamic stability and isotope effect, we demonstrate a quantitative indicator of Tgap and further a local coordination design strategy that comprises thermodynamic destabilization with vi… Show more
Due to the safety and stability of hydrogen storage alloys in the field of large-scale energy storage, it has now become a hot spot of attention for researchers. However, the...
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