1976
DOI: 10.1139/v76-391
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Isotope effects in the gas phase radiolysis of H2S and D2S

Abstract: . Can. J. Chem. 54, 2767Chem. 54, (1976. Gas phase radiolysis studies have been carried out on mixtures of H2S and D2S using as irradiation sources, either a Gammacell or a Febetron 705 pulsed electron accelerator. Separation factors (CY = (H/D)prOd i (H/D)react) were obtained for various values of xD (the mole fraction of D2S), dose rate and temperature, as well as with the addition of SFs. All of the observed CY values, for 0.2 5 xD 5 0.8, fall on the following empirical straight line.[I] CY(X,) = (1.18 f … Show more

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