Isotope Effect on Hydrogen Atom Abstraction Reaction by Recoil T Atoms in Solid n-C10D22–n-C10H22 Mixtures. Comparison of Recoil T Atoms with D Atoms in γ-Radiolysis

Abstract

An isotope effect on the hydrogen atom abstraction reaction by recoil T atoms in the n-C10D22–n-C10H22 mixtures in the solid phase is compared with the reaction by D atoms in the γ-radiolysis. A small isotope effect for the recoil T atoms is explained by a track model.