Isostere Adsorptionsenthalpien von Wasserstoff an atomar verteiltem Palladium und Platin auf Kohle

Gentsch, H.; Guillén, Nilo; Kopp, M.

doi:10.1524/zpch.1972.82.1-4.049

Search citation statements

Order By: Relevance

Paper Sections

Select...

Mechanistic Insights From Dft Calculations1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1973

2022

Publication Types

Select...

Article5

Other1

Relationship

Self Cite0

Independent6

Authors

Journals

Cited by 9 publications

(1 citation statement)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…However, according to the high barriers, a poor catalytic activity is expected in both cases, as experimentally observed for hydrogenation using single Pd atoms. 53,54 For comparison, an activation energy of 18 kcal/mol has been reported for the hydrogenation of 2-butene on a Pd 9 /CNT catalyst. 55 In this context we also verified that the Pd SA /CNT catalyst shows a very low activity for -myrcene hydrogenation (see Fig.…”

Section: Mechanistic Insights From Dft Calculationsmentioning

confidence: 99%

Control of the single atom/nanoparticle ratio in Pd/C catalysts to optimize the cooperative hydrogenation of alkenes

Rivera‐Cárcamo

Gerber

Rosal

et al. 2021

Catal. Sci. Technol.

View full text Add to dashboard Cite

show abstract

Section: Mechanistic Insights From Dft Calculationsmentioning

confidence: 99%

Control of the single atom/nanoparticle ratio in Pd/C catalysts to optimize the cooperative hydrogenation of alkenes

Rivera‐Cárcamo

Gerber

Rosal

et al. 2021

Catal. Sci. Technol.

View full text Add to dashboard Cite

show abstract

Introduction to Supported Metal Single Atom Catalysis

Minh

2022

Supported Metal Single Atom Catalysis

View full text Add to dashboard Cite

Thermal Excitation of H₂ and D₂ at Clean Metal Surfaces. Noteworthy Differences between d‐ and s‐Metals

Gentsch

Adamitzki

Ave

et al. 1982

Ber Bunsenges Phys Chem

View full text Add to dashboard Cite

UniversiatsstraBe 5 -7, 4300 Essen 1, Federal Republic of GermanyAd-and desorption measurements of hydrogen (deuterium) on clean metal surfaces under high and ultrahigh vacuum conditions by means of the capillary flow method with pressure control only by inert gauges show a small fraction of desorbing molecules in an activated state. These molecules adsorb on glass and on carbon, respectively, or are able to reduce copper-I-oxid. This experiment indicates two different ways for activation of hydrogen molecules in collision with hot metal surfaces: (i) the well known dissociation of molecules dominant at < > 1100 K and (ii) new, the excitation at hydrogen (deuterium) molecules at 800 c T, c 1100 K with activation energies of E = 0.52 (0.37) eV. The results show a significant pressure dependence of the vibration accommodation coefficient. The s-metals Cu and Au are total ineffective in dissociation and in activation molecules, respectively. The energy for excitation (H2. D2) is in accordance with the term difference of the harmonic oscillator.

show abstract

Isostere Adsorptionsenthalpien von Wasserstoff an atomar verteiltem Palladium und Platin auf Kohle

Cited by 9 publications

References 0 publications

Control of the single atom/nanoparticle ratio in Pd/C catalysts to optimize the cooperative hydrogenation of alkenes

Control of the single atom/nanoparticle ratio in Pd/C catalysts to optimize the cooperative hydrogenation of alkenes

Introduction to Supported Metal Single Atom Catalysis

Thermal Excitation of H₂ and D₂ at Clean Metal Surfaces. Noteworthy Differences between d‐ and s‐Metals

Contact Info

Product

Resources

About

Isostere Adsorptionsenthalpien von Wasserstoff an atomar verteiltem Palladium und Platin auf Kohle

Cited by 9 publications

References 0 publications

Control of the single atom/nanoparticle ratio in Pd/C catalysts to optimize the cooperative hydrogenation of alkenes

Control of the single atom/nanoparticle ratio in Pd/C catalysts to optimize the cooperative hydrogenation of alkenes

Introduction to Supported Metal Single Atom Catalysis

Thermal Excitation of H2 and D2 at Clean Metal Surfaces. Noteworthy Differences between d‐ and s‐Metals

Contact Info

Product

Resources

About

Thermal Excitation of H₂ and D₂ at Clean Metal Surfaces. Noteworthy Differences between d‐ and s‐Metals