Abstract:Sixteen isomers of heterometallic germanium clusters have been analysed in this review. There are two types of isomerism, distortion (x 15) and cis -trans (x 1) and cis -isomer contains two crystallographically independent molecules. Distortion isomers, differing only by degree of distortion in Ge -L, Ge -M (M = metal) distances and L -Ge -L (L = ligand) angles. The data are discussed with these found in the isomerism of germanium coordination compounds as well as organogermanium derivatives. In the chemistry … Show more
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