1968
DOI: 10.1021/ja01023a015
|View full text |Cite
|
Sign up to set email alerts
|

Isomerization, solvolysis, ion association, and solvation of cis- and trans-dichlorobis(ethylenediamine)cobalt(III) cations in protic and in dipolar aprotic solvents

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1

Citation Types

0
4
0

Year Published

1972
1972
1996
1996

Publication Types

Select...
4
3
1

Relationship

0
8

Authors

Journals

citations
Cited by 20 publications
(4 citation statements)
references
References 3 publications
0
4
0
Order By: Relevance
“…The observation that NH 4 Cl is significantly better than NaCl in stabilizing the β-cis isomer could be attributed to the higher ability of this salt to hydrogen bond to the β-cis isomer of the vanadium(V) anion. It is possible that one isomer must form slightly stronger interactions than the other; a VO 2 unit and one carboxylate group in the α-cis isomer may be slightly better hydrogen bond acceptors than two carboxylate groups and one oxovanadium group in the β-cis isomer .…”
Section: Resultsmentioning
confidence: 99%
“…The observation that NH 4 Cl is significantly better than NaCl in stabilizing the β-cis isomer could be attributed to the higher ability of this salt to hydrogen bond to the β-cis isomer of the vanadium(V) anion. It is possible that one isomer must form slightly stronger interactions than the other; a VO 2 unit and one carboxylate group in the α-cis isomer may be slightly better hydrogen bond acceptors than two carboxylate groups and one oxovanadium group in the β-cis isomer .…”
Section: Resultsmentioning
confidence: 99%
“…In any event, it appears that our present findings do not detract from the usefulness of the extensive contributions of Watts' school (13,(33)(34)(35)(36)(37) and others (e.g., 11) in this field, but future work should include routine checks for con.jugate base and redox pathways.…”
Section: Resultsmentioning
confidence: 56%
“…Regardless of the sophistry it is important to know the effect of solvent and counterion on the stability of isomers, and these aspects have been reviewed adequately in recent years (213). Regardless of the sophistry it is important to know the effect of solvent and counterion on the stability of isomers, and these aspects have been reviewed adequately in recent years (213).…”
Section: Certainly Effects Of This Nature Account For Large Changes mentioning
confidence: 99%