Isolation and Reactivity of Arylnickel(II) Complexes in Nickel-Catalyzed Borylation of Aryl Fluorosulfates
Manoj Kumar Sahoo,
Jeong Woo Lee,
Soochan Lee
et al.
Abstract:Aryl fluorosulfates have emerged as versatile SuFExable substrates, harnessing the reactivity of the S−F bond. In this study, we unveil their alternative synthetic utility in nickel-catalyzed borylation via C−O bond activation. This method highlights mild reaction conditions, a broad substrate scope, and moderate functional group tolerance, rendering it a practical and appealing approach for synthesizing a diverse array of aryl boronate esters. Furthermore, computational analysis sheds light on the reaction pa… Show more
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