Isolated MH stretching frequencies, anharmonicities, and dissociation energies in silanes, germanes, phosphines, and arsines

Infrared and Quantum-Chemical Studies of Dimethylsilane

“…Samples of DMS-d 0 and d 2 were available from previous work (6,8,9) and were further purified by fractional condensation. Mid infrared spectra were recorded on a Nicolet 7199 FTIR spectrometer, operating at resolutions of 0.25 or 0.5 cm −1 .…”

“…Assignments of vibrational modes used in these works were based on the early infrared and Raman studies of (CH 3 ) 2 SiH 2 (hereafter "d 0 ") and (CH 3 ) 2 SiD 2 (hereafter "d 2 ") by Ball et al (6). Subsequent work includes a far infrared study of d 0 by Durig and Hawley (7) and mid and near infrared work focused on SiH and CH stretching transitions (8)(9)(10).…”

Kinetics of the gas‐phase reaction between iodine and monogermane and the bond dissociation energy D(H3GeH)

“…On the basis of infrared data, McKean et al [3] have recently claimed that methyl substitution does significantly weaken both Si-H and Ge-H bonds. A systematic study of Ge-H bond dissociation energies should prove useful in general and help resolve this controversy in particular.…”

Rotational Analysis of the ΔvSiH=3–6 Stretching Vibrational Overtones of HSiD3

“…The first overtone, 2ν 1 , was analyzed by McKean et al (13) at medium resolution and by Boyd (14), who could partly resolve the K structure. The rotational structure of both the fundamental (11) and the first overtone (14) were found to be affected by a perturbation for J values around 13.…”