Isobaric (vapour+liquid) equilibria data for the binary systems {1,2-dichloroethane (1)+toluene (2)} and {1,2-dichloroethane (1)+acetic acid (2)} at atmospheric pressure

Hasdemir, I. Metin; Uslu, Hasan

doi:10.1016/j.jct.2006.12.003

Cited by 5 publications

(3 citation statements)

References 11 publications

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“…x 1 y 1 T (K) 1 [8]. Each temperature equilibrium datum achieved was measured with an accuracy of AE0.05 K using Fischer model-type Beckam thermometers.…”

Section: Methodsmentioning

confidence: 99%

Isobaric (vapour+liquid) equilibria data for the binary systems (toluene+acetic acid) and (toluene+methyl ethyl ketone) at atmospheric pressure

Uslu

Hasdemir

Sipahi

2009

Physics and Chemistry of Liquids

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Isobaric vapour-liquid equilibrium data have been measured for the binary systems toluene (1) þ acetic acid (2) and toluene (1) þ methyl ethyl ketone (2) at atmospheric pressure. An all-glass Fischer-Labodest-type apparatus, capable of handling pressures from 0.25 to 400 kPa and temperatures up to 523.15 K was used. The data were correlated by means of the NRTL, UNIQUAC, WILSON models and the applied UNIFAC model with satisfactory results; the relevant parameters are given and results were tested with regard to thermodynamic consistency using the methods of a modified Redlich-Kister and Herington equations.

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“…x 1 y 1 T (K) 1 [8]. Each temperature equilibrium datum achieved was measured with an accuracy of AE0.05 K using Fischer model-type Beckam thermometers.…”

Section: Methodsmentioning

confidence: 99%

Isobaric (vapour+liquid) equilibria data for the binary systems (toluene+acetic acid) and (toluene+methyl ethyl ketone) at atmospheric pressure

Uslu

Hasdemir

Sipahi

2009

Physics and Chemistry of Liquids

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“…In the other, the temperature at which acetone is saturated was 329.3 K. The greater the composition of acetone, the equilibrium temperature becomes lower towards the lowest temperature of 329.3 K, which is the saturated temperature of pure toluene. This data set was correlated with the NRTL model and Wilson equilibrium equation [6][7][8][9][10][11][12][13][14][15][16]. Then, the correlation parameters were optimized with the least square method for each phase equilibrium model ( Table 2).…”

Section: Excess Properties Of Acetone(1)/toluene(2)mentioning

confidence: 99%

“…based on the ideal liquid and gas behavior, so the VLE model should be able to predict the equilibrium properties. In this research, the difference in the solution nonideality was considered in comparison with the ideal behavior predicted by the Wilson equation and NRTL model [10][11][12][13][14]. These equations contain some parameters that are related to the properties of the chemical species.…”

mentioning

confidence: 99%