The
crystallization of struvite-K (MgKPO4·6H2O) can simultaneously recover phosphate and potassium from
source-separated urine. However, its crystal size has been rarely
reported despite significantly affecting the crystallizer performance.
Experimental results show that the average size of struvite-K was
15–63 μm in ammonium-depleted synthetic urine under the
examined conditions with a stirred reactor. A low supersaturation
ratio (S
r) or the same S
r induced by low pH and high Mg:P ratio resulted in large
crystal size. Large crystals also formed at high agitation speed,
small feed volume, or feeding close to the stirring impeller. The
size distribution of struvite-K crystals was predicted using the coupling
resolution of the population balance equation to on-site turbidity
measurement. The estimated kinetic parameters quantitatively described
the nucleation and crystal growth of struvite-K under different conditions
of supersaturation, feeding, and mixing. This work proposes approaches
to obtain large crystals while reducing fines of struvite-K.