1992
DOI: 10.1051/jp2:1992191
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Irreversible adsorption from concentrated polymer solutions

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Cited by 25 publications
(25 citation statements)
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“…Guiselin predicted that the resulting interfacial structure, which has come to be known as the "Guiselin brush," has a universal density profile, c(z) ∼ z −2/5 in good solvent. Neutron scattering [2,3] and neutron reflectivity [4,5] studies have indicated density profiles both consistent [3,5] and inconsistent [4] with this prediction.…”
mentioning
confidence: 93%
“…Guiselin predicted that the resulting interfacial structure, which has come to be known as the "Guiselin brush," has a universal density profile, c(z) ∼ z −2/5 in good solvent. Neutron scattering [2,3] and neutron reflectivity [4,5] studies have indicated density profiles both consistent [3,5] and inconsistent [4] with this prediction.…”
mentioning
confidence: 93%
“…The conformations of adsorbed or grafted chains using neutron reflectivity has been extensively studied in particular by L. Auvray and co-workers [1][2][3][4][5][6] using neutron reflectivity. Neutron reflectivity also allowed to study their interactions with a solution [7][8][9] or other soft matter systems [10]. If the adsorbed polymer chains are long enough, they can entangle with the bulk chains and thus modify the mechanical coupling between the solid surface and the liquid.…”
Section: Introductionmentioning
confidence: 99%
“…We assume that only polymer chains strongly adhered to the glass surface will remain on it after this procedure. The assumption is valid for cases in which the adsorption kinetics are fast in comparison to the diffusion of polymer chains in the solution; thus, the adsorption is irreversible and the initial chains are retained and adsorbed onto the surface [15,16].…”
Section: Step 5: Polymer Coated Glass Samplesmentioning
confidence: 99%