2024
DOI: 10.1038/s41467-024-50507-6
|View full text |Cite
|
Sign up to set email alerts
|

Iron photocatalysis via Brønsted acid-unlocked ligand-to-metal charge transfer

Xiaoyu Jiang,
Yu Lan,
Yudong Hao
et al.

Abstract: Reforming sustainable 3d-metal-based visible light catalytic platforms for inert bulk chemical activation is highly desirable. Herein, we demonstrate the use of a Brønsted acid to unlock robust and practical iron ligand-to-metal charge transfer (LMCT) photocatalysis for the activation of multifarious inert haloalkylcarboxylates (CnXmCOO−, X = F or Cl) to produce CnXm radicals. This process enables the fluoro-polyhaloalkylation of non-activated alkenes by combining easily available Selectfluor as a fluorine sou… Show more

Help me understand this report
View preprint versions

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

2024
2024
2024
2024

Publication Types

Select...
3

Relationship

0
3

Authors

Journals

citations
Cited by 3 publications
references
References 70 publications
0
0
0
Order By: Relevance