AA5657 alloy is one of the important members of 5xxx-series alloys. It has application in many fields as packing, electricity, architectural, and printing. These applications require high quality surface finishing, and the alloy ingots require homogeneous microstructure. In the industry of DC (direct-chill) casting of lxxx and 5xxx-series aluminium ingots, there exist different cooling rates from the casting surface to the ingot center. Thus, different Fe intermetallic phases such as AlmFe, A^Fe, a-AlFeSi and A^Fe can form preferentially in different positions of the ingot.The Fe intermetallic phase transition in DC casting ingot may cause microstructure inhomogeneities, which in turn cause the so called fir-tree zones (FTZs) in the ingots as well as streaks and bands on the Al sheets.Nowadays, with the increase of impurity in aluminium smelting raw materials (coke, alumina, etc.), the levels of trace elements present in the primary metal is gradually increasing. The impact of this increase on the aluminium transformation process and the final products is uncertain. Thus, there is a clear need to better understand these impacts, which will allow identifying ways to mitigate the negative impacts.The study presented in this thesis was performed on AA5657 alloys to study the