2018
DOI: 10.1002/ange.201712999
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IR Spectrum and Structure of Protonated Monosilanol: Dative Bonding between Water and the Silylium Ion

Abstract: We report the spectroscopic characterization of protonated monosilanol (SiH3OH2+) isolated in the gas phase, thus providing the first experimental determination of the structure and bonding of a member of the elusive silanol family. The SiH3OH2+ ion is generated in a silane/water plasma expansion, and its structure is derived from the IR photodissociation (IRPD) spectrum of its Ar cluster measured in a tandem mass spectrometer. The chemical bonding in SiH3OH2+ is analyzed by density functional theory (DFT) cal… Show more

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Cited by 4 publications
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