Ionothermal synthesis, characterization of a new layered gallium phosphate with an unusual heptamer SBU

Huang, Liangliang; Ma, Yike; Jiao, Shufei; Jiang, Yansong; Bi, Yanfeng

doi:10.1016/j.jssc.2017.07.010

Cited by 7 publications

(2 citation statements)

References 39 publications

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“…Gao et al used also a deep eutectic solvent to synthesize the first new layered gallium phosphate material, which consists of an unusual heptamer secondary building units (SBU) and exhibits photoluminescence properties as a solid at room temperature [142]. We particularly observed the morphologies of ZSM-5 molecular sieves with MFI structure that were prepared by the hydrothermal process and compared them with those made by the ionothermal method, as shown in figure 10.…”

Section: The Effect Of Competition In Forming the Frameworkmentioning

confidence: 99%

A review on ionothermal synthesis of zeolites and zeotype materials

Fortas,

Boukoussa,

Hasnaoui

et al. 2024

Phys. Scr.

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Known as green inorganic products and environmentally beneficial, ionic liquids (ILs) are increasingly used in the ionothermal synthesis of zeolites and zeotype materials compared to the hydrothermal method. This safe and successful process offers new opportunities to produce several molecular sieves with different morphologies and structures for promising applications.In this review, we summarize the history of the most successful phases of zeolites and zeotype materials, with different structures such as AEL, AEI, AFI, AST, ATS, CHA, -CLO, ITW, LEV, LTA, MFI, MTN, MTT, SOD, TON, IRR, and STW, from ILs discovery until 2022. The use of the ionothermal method compared to the hydrothermal route is evaluated and reported in this paper, besides synthesis parameters affecting the final product formation, such as IL dosage, cation size and shape, water content, (P, Si, F, IL/Al) ratios, crystallization time and temperature, mineralizing agent, Me/Al ratio, the addition of a secondary template (co-SDA), the use of IL as both SDA and solvent, competition in forming the framework, and the use of eutectic mixture and deep eutectic solvent (DES). Furthermore, we collected the various applications of these materials and highlighted the advantages of the ionothermal process, offering a comprehensive understanding of this topic.

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Section: The Effect Of Competition In Forming the Frameworkmentioning

confidence: 99%

A review on ionothermal synthesis of zeolites and zeotype materials

Fortas,

Boukoussa,

Hasnaoui

et al. 2024

Phys. Scr.

View full text Add to dashboard Cite

show abstract

“…Following this work, other inorganic phosphate-based architectures have been described. [64][65][66][67][68] Interestingly, using reline, a phosphonate-based MOF could also be prepared. 69 The latter, formulated [Zn(CMPhos)](NH4), was obtained by heating at 80°C the carboxymethylphosphonate ligand CMPhos (Scheme 1) and Zn(NO3)2 in reline.…”

Section: Phosphonate-based Mofsmentioning

confidence: 99%