Ionothermal Syntheses, Crystal Structures and Luminescence of Two Lanthanide‐Carboxylate Frameworks based on the 1, 4‐Naphthalenedicarboxylate and Oxalate Mixed Ligands

Ionothermal synthesis employs ionic liquids for synthesis of metal organic frameworks (MOFs) as solvent and template. The cations and anions of ionic liquids may be finely adjusted to produce a great variety of reaction environments and thus frameworks. Organisation of the structures synthesised from related ionic liquid combinations give rise to provocative chemical trends that may be used to predict future outcomes. Further analysis of their structures is possible by reducing the complex framework to its underlying topology, which by itself brings more precision to prediction. Through reduction, many seemingly different, but related classes of structures may be merged into larger groups and provide better understanding of the nanoscopic structures and synthesis conditions that gave rise to them. Ionothermal synthesis has promised to enable us to effectively plan the synthesis ahead for a given purpose. However, for its promise to be kept, several difficult limitations must be overcome, including the inseparable cations from the solvent that reside in the framework pore.

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Ionothermal Syntheses, Crystal Structures and Luminescence of Two Lanthanide‐Carboxylate Frameworks based on the 1, 4‐Naphthalenedicarboxylate and Oxalate Mixed Ligands

Cited by 2 publications

References 22 publications

Coordination Chemistry in Ionic Liquids: A Review

Coordination Chemistry in Ionic Liquids: A Review

Ionothermal Synthesis of Metal-Organic Framework

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