Ionospheric modification using photochemically reactive vapors is studied with a one-dimensional, multi-ion, fluid model of plasma flow along magnetic field lines. The magnitudes of ion and electron density changes are determined by considering both chemical processes (i.e., photoionization, ion-molecule reactions, dissociative recombination, electron attachment) and transport processes (i.e., multispecies diffusion, electric currents, ambipolar electric fields). The numerical treatment in the model is not specific to any type of release or any interaction chemistry. It has been used to simulate releases of Ba, CO2, and CF3Br in the ionosphere, but generalization to other species may be easily accomplished. The results of the calculations are found to be in good agreement with experimental observations. The feasibility of modifying the parallel current paths in the auroral F region is examined.
INTRODUCTION
Simulation of ionospheric modification by chemical releases is complicated by (1) the gas dynamics of the neutral release, (2) the creation of new species by chemical reactions between the released species and the background atmosphere, and (3) the electrodynamics of the modified plasma. Each of these areas has been examined with numerical and analytical models. An overview of the neutral gas dynamics of chemical releases has been given by Bernhardt et al. [1988a]. Kinetic theory has been used to represent the neutral flow of the released gas in the rarefied background atmosphere [Bernhardt, 1979a; Thompson, 1989]. Fluid representations of the injected gas interactions have been described by Schunk [1978], Bernhardt [1982], Yau [1984], and Bernhardt et al. [1988a]. Thermodynamic representations of condensation in the gas expansions have been described by Bernhardt [1982, 1987]. In this paper a simple diffusion model is used to describe the neutral gas expansion. The chemistry of neutral releases in the ionosphere is complex, requiring many reactions involving multiple ion species. Bernhardt [1987] has compared sets of two-body reactions for six ionospheric depletion chemicals. For chemical releases that yield positive-ion-intermediary (PII) species, tens of reactions and product species are required to describe the chemistry [Sjolander and Szuczewicz, 1979; Johnson et al., 1980; Yau et al., 1985; Zinn et al., 1982; Bernhardt et al., 1988b]. As an example of a release that produce negative-ion-intermediary (NII) species, an SF 6 gas cloud injected into an O +, e-plasma requires 14 reactions and nine species [Mendillo and Forbes, 1982; Bernhardt, 1984; Bernhardt et al., 1986]. The importance of three-body reactions during the early phase of ionospheric modification is discussed by Yau et al. [1985]. Here, the computational This paper is not subject to U.S. copyright. Published in 1991 by the American Geophysical Union. Paper number 91JA01424.
examples are limited to two-body reactions between three plasma species, but extension to larger numbers of reactions and species is easily accomplished with our formulatio...