Ionization potentials of carbon tetraiodide and tetraiodoethylene in the solid state

Sato, Naoki; Inokuchi, Hiroo

doi:10.1016/0301-0104(87)80009-5

Cited by 9 publications

(4 citation statements)

References 24 publications

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“…The observed large value of the ionization potential, found by ultraviolet spectroscopy, was explained also by the presence of this bond [20]. Recently, this system was exploited as a model for packing tetrahedra [19].…”

Section: Introductionmentioning

confidence: 81%

“…Concerning the short-range behaviour, the I-I maxima are at 4.05, 4.4 and 6.6Å; the first and the last ones are distinct. Although the peak at 4.05Å appears, which should possess a crucial role in explaining the formation of the tetragonal lattice [11,20], it is not so well defined in terms of pair correlations. In contrast, the carbon-iodine peak at 4.5Å looks much more characteristic.…”

Section: Partial Radial Distribution Functionsmentioning

confidence: 97%

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Large-aperture electrooptic switches with cylindrical electrodes

Zanadvorov¹,

Malinov²,

Starikov³

1988

Sov. J. Quantum Electron.

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Total scattering neutron powder diffraction measurements were performed on the tetragonal phase (a = 6.4202(5)Å, c = 9.5762(12)Å) of CI 4 . The experiments were followed by reverse Monte Carlo (for powder diffraction) modelling. Detailed analyses of the resulting particle configurations revealed that the observed diffuse scattering originates from the libration of the molecules. By examining the partial radial distribution functions a distinct carbon-iodine peak at 4.5Å is found, which appears as a consequence of corner-to-face mutual alignment of two molecules. The occurrence of edge-to-edge alignments is also significant within the first carbon-carbon coordination shell.

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Section: Introductionmentioning

confidence: 81%

Section: Partial Radial Distribution Functionsmentioning

confidence: 97%

Large-aperture electrooptic switches with cylindrical electrodes

Zanadvorov¹,

Malinov²,

Starikov³

1988

Sov. J. Quantum Electron.

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show abstract

“…Concerning the short-range behaviour, the I-I maxima are at 4.05, 4.4 and 6.6 Å; the first and the last ones are distinct. Although the peak at 4.05 Å appears, which should possess a crucial role in explaining the formation of the tetragonal lattice [11,20], it is not so well defined in terms of pair correlations. In contrast, the carbon-iodine peak at 4.5 Å looks much more characteristic.…”

Section: Partial Radial Distribution Functionsmentioning

confidence: 96%

“…Considering existing knowledge on XI 4 type crystals [14,15,16,17,18,19] that possess a cubic symmetry, this unusual structure has been explained by the close packing of I atoms and by an intermolecular I − I bond [11]. The observed large value of the ionization potential, found by ultraviolet spectroscopy, was explained also by the presence of this bond [20]. Recently, this system was exploited as a model for packing tetrahedra [19].…”

Section: Introductionmentioning

confidence: 99%

The origin of diffuse scattering in crystalline carbon tetraiodide

Temleitner¹,

Pusztai²

2013

J. Phys.: Condens. Matter

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Total scattering neutron powder diffraction measurements were performed on the tetragonal phase (a=6.4202(5) Å, c=9.5762(12) Å) of CI4. The experiments were followed by reverse Monte Carlo (for powder diffraction) modelling. Detailed analyses of the resulting particle configurations revealed that the observed diffuse scattering originates from the libration of the molecules. By examining the partial radial distribution functions a distinct carbon-iodine peak at 4.5 Å is found, which appears as a consequence of corner-to-face mutual alignment of two molecules. The occurrence of edge-to-edge alignments is also significant within the first carbon-carbon coordination shell.

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Molecular Electronic Relaxation in Organic Solids

Sato

1997

Electrical and Related Properties of Organic Solids

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Ionization potentials of carbon tetraiodide and tetraiodoethylene in the solid state

Cited by 9 publications

References 24 publications

Large-aperture electrooptic switches with cylindrical electrodes

Large-aperture electrooptic switches with cylindrical electrodes

The origin of diffuse scattering in crystalline carbon tetraiodide

Molecular Electronic Relaxation in Organic Solids

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