Ionic-liquid-modified magnetite nanoparticles for MSPE-GC-MS determination of 2,4-D butyl ester and its metabolites in water, soil, and bottom sediments

Gubin, A. S.; Sukhanov, P. T.; Кушнир, А. А.; Shikhaliev, Kh. S.; Potapov, Mikhail A.; Ковалева, Е. Н.

doi:10.1016/j.enmm.2022.100652

Cited by 7 publications

(4 citation statements)

References 44 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The application of ILs for sample pre-concentration and extraction is widely considered the future direction of pesticide residue analysis, and numerous studies have already been conducted in this area. These studies encompass various techniques, including dispersive liquid-liquid microextraction (DLLME) [62][63][64][65][66][67][68], solid-phase extraction (SPE) [69][70][71], solidphase microextraction (SPME) [72][73][74][75][76], and so on. ILs demonstrate significant potential for improving the efficiency and accuracy of pesticide residue analysis, presenting a promising avenue for addressing the challenges associated with trace polar contaminant analysis in diverse samples.…”

Section: Ils As Solventmentioning

confidence: 99%

“…Material modification is a technique that involves altering the original properties of a material through physical and chemical means, thereby imparting different characteristics to the material [61,92,99]. Due to their superior physical properties and design flexibility for structural purposes, ILs are commonly employed in material modification processes [71][72][73][74][75][76][80][81][82]106]. In modes such as solid-phase extraction, solid-phase microextraction, and dispersive micro-solid-phase extraction, IL-modified materials are currently utilized as extraction phases.…”

Section: Materials Modificationmentioning

confidence: 99%

“…IL-modified materials can also be employed in magnetic extraction procedures [108]. For instance, Gubin et al developed a magnetic absorbent based on magnetite nanoparticles modified with an IL [76]. The pollution levels of soil, groundwater, river water, and bottom sediment due to 2,4-DB and its metabolites were assessed using a combination of magnetic solid-phase extraction (MSPE) and gas chromatography-mass spectrometry (GC-MS).…”

Section: Materials Modificationmentioning

confidence: 99%

See 2 more Smart Citations

Applications of Ionic Liquids in the Field of Agriculture: A Review

Wang,

Qin,

Dong

et al. 2023

Agriculture

View full text Add to dashboard Cite

This review delves into the diverse applications of ionic liquids (ILs) in modern agriculture, focusing on their pivotal roles in the extraction of natural products and pesticides, as well as their substantial significance in sustainable pesticide delivery systems. The reported extraction methods include ILs and their modified materials as solvents in dispersive liquid–liquid microextraction, solid-phase dispersion, and solid-phase microextraction. The study categorizes ILs according to their utility as herbicides, microbicides, food repellents, and plant growth regulators. This review investigates the use of ILs as plant immunity inducers to elevate the systemic acquired resistance in crops, thereby augmenting their intrinsic ability to defend against plant pathogens. Furthermore, the review explores the application of ILs in pesticide delivery systems, emphasizing their ability to enhance efficacy while promoting environmental sustainability. The biodegradability and toxicity aspects of ILs are also discussed, shedding light on their potential as eco-friendly alternatives in agricultural practices. In conclusion, this comprehensive overview underscores the multifaceted contributions of ILs in agriculture, from efficient extraction methods to the development of innovative and sustainable pesticide delivery systems. As the agricultural landscape evolves towards environmentally conscious practices, the integration of ILs presents a promising avenue for enhancing productivity while minimizing ecological impact. As the agricultural industry seeks innovative and sustainable solutions, the nuanced exploration of ILs in this review highlights their potential to address multiple challenges in modern farming practices.

show abstract

Section: Ils As Solventmentioning

confidence: 99%

Section: Materials Modificationmentioning

confidence: 99%

Section: Materials Modificationmentioning

confidence: 99%

See 1 more Smart Citation

Applications of Ionic Liquids in the Field of Agriculture: A Review

Wang,

Qin,

Dong

et al. 2023

Agriculture

View full text Add to dashboard Cite

show abstract

“…Herbicides are practical tools for weed management in an agricultural system. However, long-term use of chemical herbicides endangers the environment and public health and fosters herbicide-resistant organisms . Therefore, developing green chemicals for weed management is critical to mitigating the adverse effects of pesticides and maximizing wheat yield and quality.…”

Section: Introductionmentioning

confidence: 99%

Novel Finding on How Melatonin and Nanoselenium Alleviate 2,4-D Butylate Stress in Wheat Plants

Zhou,

Zhang,

Miao

et al. 2023

J. Agric. Food Chem.

View full text Add to dashboard Cite

Nanoselenium (nano-Se) or melatonin (MT) foliar spray reduces pesticide stress by stimulating plant secondary metabolism and antioxidant capacity. However, the effects of nano-Se and MT biofortification on the interaction between plant secondary metabolic pathways and rhizosphere microbes in mitigating 2,4-D butyrate stress remain unknown. Compared to nano-Se or MT treatment alone, nano-Se and MT combined application increased the antioxidant enzyme activities and decreased the MDA (25.0%) and H 2 O 2 (39.3%) contents with 2,4-D butylate exposure. Importantly, they enhance the soil enzymes (S-FDA by 53.1%), allelochemicals (luteolin by 164.1% and tricin by 147.3%), as well as plant secondary metabolites (JA by 63.3% and 193.3% in leaves and roots) levels. It also improved the beneficial microbial abundance of Comamonadaceae, Sphingomonadaceae, and Rhodobacteraceae in the rhizosphere soil. In conclusion, nano-Se and MT alleviate 2,4-D butylate stress in wheat plants by enabling the interaction between rhizosphere microorganisms, allelopathic substances, and secondary metabolites.

show abstract