Ionic liquid modified carbon nanotube supported palladium nanoparticles for efficient Sonogashira-Hagihara reaction

Glucose electrooxidation modelling studies on carbon nanotube supported Pd catalyst with response surface methodology and density functional theory

“…Electrocatalytic properties and glucose oxidation kinetics of metal electrocatalysts are highly dependent on the effective surface area [12,13]. The loading of metal catalysts on carbon-based materials increases the electrocatalytic activity for glucose oxidation [14][15][16]. As a catalyst support material, CNTs have superior properties such as large surface area, electrochemical stability, and high electrical conductivity [17,18].…”

Stabilized Palladium Nanoparticles from Bis-(N-benzoylthiourea) Derived-PdII Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water

“…Final compounds 14a – f were isolated and purified by flash chromatography (silica gel) using mixtures of n -hexane/EtOAc as eluent. They offered matching spectroscopic data with the analogous ones obtained in the literature [ 28 ].…”

“…The Sonogashira–Hagihara cross-coupling reaction ( Scheme 6 ) was next assessed using these two palladium catalyst precursors. Using the parameters displayed by our group [ 28 ], the optimization was performed with phenylacetylene ( 13a ) and 4-iodoanisole ( 3a ). The employment of 90 °C, DABCO as a base in water for 10 h afforded compound 14a in 91% yield in the presence of the catalyst generated by 1 ( Table 6 , entry 1op).…”

Pd Nanoparticles Decorated on Ionic Liquid Modified Magnetite Nanoparticles as a Recyclable and Active Nanocatalyst for Reduction of Nitro Compounds and Degradation of Organic Dyes

“…c Supporting information). In the next step, Fe 3 O 4 @SiO 2 @SH NPs were prepared and reacted with IL (IL 3) [41] via Thiol‐Ene reaction [42] (Scheme 2). Finally, Pd magnetic nanocomposite was prepared by stabilization of Pd nanoparticles on the surface of Fe 3 O 4 @SiO 2 @IL.…”