Ionic liquid-derived zinc tetrahalide complexes: structure and application to the coupling reactions of alkylene oxides and CO2

Palgunadi, Jelliarko; Kwon, Ohsuk; Lee, Hyunjoo; Bae, Jangho; Ahn, Byoung Sung; Min, Na-Young; Kim, Hoon Sik

doi:10.1016/j.cattod.2004.09.005

Cited by 69 publications

(37 citation statements)

References 18 publications

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“…Palgunadi et al [55] reported a series of bis(1-alkyl-3-methylimidazolium) tetrahalide Zn complexes for the coupling of CO 2 with various epoxides. The influence of halides on the reaction was investigated.…”

Section: Metal-based Ionic Liquidsmentioning

confidence: 99%

Ionic Liquids: The Synergistic Catalytic Effect in the Synthesis of Cyclic Carbonates

Cheng

Wang

et al. 2013

Catalysts

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This review presents the synergistic effect in the catalytic system of ionic liquids (ILs) for the synthesis of cyclic carbonate from carbon dioxide and epoxide. The emphasis of this review is on three aspects: the catalytic system of metal-based ionic liquids, the catalytic system of hydrogen bond-promoted ionic liquids and supported ionic liquids. Metal and ionic liquids show a synergistic effect on the cycloaddition reactions of epoxides. The cations and anions of ionic liquids show a synergistic effect on the cycloaddition reactions. The functional groups in cations or supports combined with the anions have a synergistic effect on the cycloaddition reactions. Synergistic catalytic effects of ILs play an important role of promoting the cycloaddition reactions of epoxides. The design of catalytic system of ionic liquids will be possible if the synergistic effect on a molecular level is understood.

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Section: Metal-based Ionic Liquidsmentioning

confidence: 99%

Ionic Liquids: The Synergistic Catalytic Effect in the Synthesis of Cyclic Carbonates

Cheng

Wang

et al. 2013

Catalysts

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“…Zinc tetrahalide ILs also showed notable activity for the reaction. Similar cooperative actions of the Zn center of [ZnX 2 Y 2 ] 2− (Lewis acid) and a halide anion (Lewis base) liberated from the dianion were proposed for the epoxide ring opening [15,16,21]. [36].…”

Section: Co 2 Cycloaddition Catalyzed By Ils With Lewis Acidsmentioning

confidence: 76%

Ionic Liquids in Green Carbonate Synthesis

Sun¹,

Liu²,

Fujita³

et al. 2011

Ionic Liquids - Classes and Properties

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“…In this work, a mononuclear zinc complex ZnLCl 2 is reported. Zinc complexes bearing various ancillary ligands have been applied in the catalysis of the copolymerization of cyclohexene oxide and CO 2 [1][2][3]. The asymmetric unit of the title complex contains one independent neutral complex molecule, which consists of one center zinc ion, one bidentate ligand and two chlorido ligands.…”

Section: Discussionmentioning

confidence: 99%

Crystal structure of dichlorido(2-(1-methyl-1H-benzo[d]imidazol-2-yl)aniline-κ² N,N′)zinc(II)

Zhou

Zhang

et al. 2016

Zeitschrift Für Kristallographie - New Crystal Structures

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Ionic liquid-derived zinc tetrahalide complexes: structure and application to the coupling reactions of alkylene oxides and CO2

Cited by 69 publications

References 18 publications

Ionic Liquids: The Synergistic Catalytic Effect in the Synthesis of Cyclic Carbonates

Ionic Liquids: The Synergistic Catalytic Effect in the Synthesis of Cyclic Carbonates

Ionic Liquids in Green Carbonate Synthesis

Crystal structure of dichlorido(2-(1-methyl-1H-benzo[d]imidazol-2-yl)aniline-κ² N,N′)zinc(II)

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Ionic liquid-derived zinc tetrahalide complexes: structure and application to the coupling reactions of alkylene oxides and CO2

Cited by 69 publications

References 18 publications

Ionic Liquids: The Synergistic Catalytic Effect in the Synthesis of Cyclic Carbonates

Ionic Liquids: The Synergistic Catalytic Effect in the Synthesis of Cyclic Carbonates

Ionic Liquids in Green Carbonate Synthesis

Crystal structure of dichlorido(2-(1-methyl-1H-benzo[d]imidazol-2-yl)aniline-κ2 N,N′)zinc(II)

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Crystal structure of dichlorido(2-(1-methyl-1H-benzo[d]imidazol-2-yl)aniline-κ² N,N′)zinc(II)