Ion transfer across liquid|liquid interface under forced hydrodynamic conditions. I: Digital simulations

Chunks of Charge: Effects at Play in the Assembly of Macromolecules at Fluid Surfaces

“…Fluid interfaces are a platform for a variety of important processes that include interface-catalyzed reactions, , ion transfer, , nanoparticle synthesis and assembly, − oil recovery and water remediation, and biological processes that occur at the interface between a fluid cell membrane and water. , These processes often depend on the adsorption and assembly of ionizable macromolecules to the interface between a nonpolar fluid and water.…”

Facilitated proton transfer across liquid | liquid interfaces under forced hydrodynamic conditions. Determination of partition coefficients of neutral weak bases

“…Recently, we presented the general equations for a model that describes ion transfer reactions across the oil|water interface assisted by a neutral ligand, under FHCs. The model was solved numerically using explicit finite difference and the results of numerical simulations were obtained for simple and facilitated ion transfer [61]. As expected, the flow pattern in the experimental setup plays an important role over the mass transport phenomena within the ITIES cell.…”

“…The one-dimensional model used to develop the proposed methodology is a revised and extended version of the model proposed by Ovejero et al [61] and it is described in detail in the Supplementary Material (Section A1 and A2).…”

Effect of ligand protonation on the facilitated ion transfer reactions across oil|water interfaces. V. Applications of forced hydrodynamic conditions

“…Recently, we presented the general equations for a model that describes ion transfer reactions across the oil|water interface assisted by a neutral ligand, under forced hydrodynamic conditions. Analysis was mainly focused on the effect of mechanical stirring of the aqueous or organic phase during the potential sweep, and its influence on the limiting diffusion currents [67].…”