Modern Electrochemistry 1 2002
DOI: 10.1007/0-306-46909-x_2
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Ion-Solvent Interactions

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“…The ethanol spraying implies a decrease of the total resistance of the systems (Figure 10a,c,d,f). A Grotthus-like proton "jumping" conduction mechanism [60], mediated by hydrogen bonding with the PVP-and Citrate-capped Au NPs [61,62], may be responsible for the higher charge transport rate (i.e., lower overall resistance) caused by the ethanol/water solution. Nonetheless, a low-water ionic product (K w = 10 −14 ) and ethanol small acid constant (pK a = 16) still pinned the overall resistance in the tens of MΩ range.…”
Section: Electrical Measurementsmentioning
confidence: 99%
“…The ethanol spraying implies a decrease of the total resistance of the systems (Figure 10a,c,d,f). A Grotthus-like proton "jumping" conduction mechanism [60], mediated by hydrogen bonding with the PVP-and Citrate-capped Au NPs [61,62], may be responsible for the higher charge transport rate (i.e., lower overall resistance) caused by the ethanol/water solution. Nonetheless, a low-water ionic product (K w = 10 −14 ) and ethanol small acid constant (pK a = 16) still pinned the overall resistance in the tens of MΩ range.…”
Section: Electrical Measurementsmentioning
confidence: 99%