Ion-Conductive and Elastic Slide-Ring Gel Li Electrolytes Swollen with Ionic Liquid

Sugihara, Naoki; Nishimura, Kirara; Nishino, Haruka; Kanehashi, Shinji; Mayumi, Koichi; Tominaga, Yoichi; Shimomura, Takeshi; Ito, Kohzo

doi:10.1016/j.electacta.2017.01.118

Cited by 32 publications

(11 citation statements)

References 76 publications

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“…The swelling also determines the amount of plasticizer and salt components present in the PE, which decides the overall electrochemical properties. [314][315][316] For example, the ionic conductivity is increased with an increase in LE content; at the same time, swelling of the polymer film induces volume expansion due to the uncoiling or unpacking of the polymer chains from the ordered phases (crystalline) of the polymer matrix. This phenomenon decreases the mechanical properties; nevertheless, the solvent uptake increases the mobile phase within the polymer electrolyte.…”

Section: The Ex Situ Process and Device Fabrication Thereofmentioning

confidence: 99%

In situpolymerization process: an essential design tool for lithium polymer batteries

Vijayakumar

Anothumakkool

Kurungot

et al. 2021

Energy Environ. Sci.

211

121

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Section: The Ex Situ Process and Device Fabrication Thereofmentioning

confidence: 99%

In situpolymerization process: an essential design tool for lithium polymer batteries

Vijayakumar

Anothumakkool

Kurungot

et al. 2021

Energy Environ. Sci.

211

121

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“…Up until now, numerous polymer/ liquid hybrid electrolytes along with the individual components have been studied and reported with equal intensity. These include polymer matrixes such as polyethylene oxide (PEO) and its derivate [73], poly(vinylidene fluoride) (PVDF) [74], poly(ethylene glycol) diacrylate (PEGDMA) [75], polymeric ionic liquid (PIL) and so on [76], as well as conventional liquid electrolytes and ionic liquids [77][78][79]. Here, the study of the liquid ingredients in polymer matrixes has been mainly devoted to the resolution of the diffusion issue as well as the realization of better interfacial adhesion between the two electrodes.…”

Section: Polymer/liquid Hybrid Electrolytesmentioning

confidence: 99%

Recent Advancements in Polymer-Based Composite Electrolytes for Rechargeable Lithium Batteries

Tan

Zeng

et al. 2018

Electrochem. Energ. Rev.

324

170

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In recent years, lithium batteries using conventional organic liquid electrolytes have been found to possess a series of safety concerns. Because of this, solid polymer electrolytes, benefiting from shape versatility, flexibility, low-weight and low processing costs, are being investigated as promising candidates to replace currently available organic liquid electrolytes in lithium batteries. However, the inferior ion diffusion and poor mechanical performance of these promising solid polymer electrolytes remain a challenge. To resolve these challenges and improve overall comprehensive performance, polymers are being coordinated with other components, including liquid electrolytes, polymers and inorganic fillers, to form polymer-based composite electrolytes. In this review, recent advancements in polymer-based composite electrolytes including polymer/ liquid hybrid electrolytes, polymer/polymer coordinating electrolytes and polymer/inorganic composite electrolytes are reviewed; exploring the benefits, synergistic mechanisms, design methods, and developments and outlooks for each individual composite strategy. This review will also provide discussions aimed toward presenting perspectives for the strategic design of polymer-based composite electrolytes as well as building a foundation for the future research and development of high-performance solid polymer electrolytes.

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“…Moreover, ILs are also known for their tunable properties [12,13]. These excellent properties of ILs have resulted into their wide applications such as catalytic [14,15], synthesis [16], electrochemistry [17], heat transfer systems [18,19], and energy storage [20]. It is estimated that by combining different anions and cations, over 10 18 different ternary ILs can be formed [11].…”

Section: Introductionmentioning

confidence: 99%

ANN Modeling of Thermal Conductivity and Viscosity of MXene-Based Aqueous IoNanofluid

Parashar¹,

Aslfattahi

Yahya³

et al. 2021

Int J Thermophys

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Research shows that due to enhanced properties IoNanofluids have the potential of being used as heat transfer fluids (HTFs). A significant amount of experimen-tal work has been done to determine the thermophysical and rheological properties of IoNanofluids; however, the number of intelligent models is still limited. In this work, we have experimentally determined the thermal conductivity and viscosity of MXene-doped [MMIM][DMP] ionic liquid. The size of the MXene nanoflakes was determined to be less than 100 nm. The concentration was varied from 0.05 mass% to 0.2 mass%, whereas the temperature varied from 19 °C to 60 °C. The maximum thermal conductivity enhancement of 1.48 was achieved at 0.2 mass% and 30 °C temperature. For viscosity, the maximum relative viscosity of 1.145 was obtained at 0.2 mass% and 23 °C temperature. After the experimental data for thermal conductivity and viscosity were obtained, two multiple linear regression (MLR) mod-els were developed. The MLR models' performances were found to be poor, which further called for the development of more accurate models. Then two feedforward multilayer perceptron models were developed. The Levenberg-Marquardt algorithm was used to train the models. The optimum models had 4 and 10 neurons for thermal conductivity and viscosity model, respectively. The values of statistical indices showed the models to be well-fit models. Further, relative deviations values were also accessed for training data and testing data, which further showed the models to be well fit.

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Ion-Conductive and Elastic Slide-Ring Gel Li Electrolytes Swollen with Ionic Liquid

Cited by 32 publications

References 76 publications

In situpolymerization process: an essential design tool for lithium polymer batteries

In situpolymerization process: an essential design tool for lithium polymer batteries

Recent Advancements in Polymer-Based Composite Electrolytes for Rechargeable Lithium Batteries

ANN Modeling of Thermal Conductivity and Viscosity of MXene-Based Aqueous IoNanofluid

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