Thermally induced transformations at an ion implanted α-Fe2O3/α-Al2O3 interface: A Mössbauer spectroscopy study Thin Fe 2 O 3 layers ͑44 and 55 nm͒ were deposited by pulsed excimer laser ablation on single-crystal alumina ͑␣-Al 2 O 3 ͒ substrates heated at 675°C. The ion beam mixing of these ␣-Fe 2 O 3 /␣-Al 2 O 3 couples was carried out using 300 keV Kr 3ϩ ions at a fluence of 2ϫ10 16 ions/cm 2 . The mixing effect was followed by Rutherford backscattering spectrometry ͑RBS͒, conversion electron Mössbauer spectroscopy, and grazing incidence x-ray diffraction method. RBS spectra do not show any evidence of mixing at the interface, whereas the data obtained with the two other techniques display phases like oxygen deficient Fe 3 O 4 , Fe 3Ϫy Al y O 4 , and Fe 1ϩx Al 2Ϫx O 4 . For this last phase, x is determined as being equal to about 0.5. It is shown that ion beam mixing is more efficient for the thinner Fe 2 O 3 layer, in accordance with the projected range of the Kr 3ϩ ions.