Ion-Beam Archaeometry of Islamic Lustre Glazes

Jarjis, R.A.

doi:10.4028/www.scientific.net/kem.132-136.1434

Cited by 6 publications

(5 citation statements)

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“…Numerous publications discuss the chemical and structural composition of archaeological lusters layers, 3–8 but no data have yet been published on contemporary lusters. That is the aim of this paper.…”

Section: Introductionmentioning

confidence: 99%

Contemporary Golden‐Like Lusters on Ceramics: Morphological, Chemical, and Structural Properties

Helary

Darque-Ceretti

Aucouturier

2005

Journal of the American Ceramic Society

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This paper describes an investigation on contemporary luster layers produced by a Spanish craftsman who is working on reproducing the traditional Islamic recipes. Various analytical investigations (AFM, HR‐SEM, PIXE, RBS, TEM, XPS, GIXRD) were carried out. The aim of this study is to establish the chemical nature and physical structure of the luster layer constituted by silver and copper particles of nanometric dimensions. This information is used to expand on a formation model of a luster layer.

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Section: Introductionmentioning

confidence: 99%

Contemporary Golden‐Like Lusters on Ceramics: Morphological, Chemical, and Structural Properties

Helary

Darque-Ceretti

Aucouturier

2005

Journal of the American Ceramic Society

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“…However, in these cases, neither the metallic character of the particles nor their crystalline character were demonstrated. Recently, Rutherford backscattering analysis of a luster ceramic surface suggested that the layer thickness was ϳ0.3 m. 19 No detailed studies followed these preliminary results, and information on luster properties and composition is still scarce and fragmented.…”

Section: Introductionmentioning

confidence: 99%

Luster Pottery from the Thirteenth Century to the Sixteenth Century: A Nanostructured Thin Metallic Film

Pérez-Arantegui

Molerà

Larrea

et al. 2001

Journal of the American Ceramic Society

153

123

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Luster is a decorative metallic film that was applied on the surface of medieval glazed pottery. It can be obtained via the low-temperature (ϳ650°C), controlled reduction of copper and silver compounds. In this paper, we show that luster is a thin layered film (200 -500 nm thick) that contains metallic spherical nanocrystals dispersed in a silicon-rich matrix and has a metal-free outermost glassy layer that is 10 -20 nm thick. Silver nanocrystals seem to be separated from those of copper, forming aggregates 5-100 m in diameter. This composite structure exhibits optical properties that are dependent on both the particle size and the matrix. Luster is indeed the first reproducible nanostructured thin metallic film that was made by humans.

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“…17,18 Similar procedures have been employed for fitting the RBS data from historical lusters. [32][33][34] To determine the luster depth composition profiles, a sequence of layers with varying silver and/or copper content was modeled. The depth concentration profiles of the luster layers were fitted using between 10 and 15 layers of varying thickness and silver/copper content.…”

Section: Materials and Techniquesmentioning

confidence: 99%

Composition, nanostructure, and optical properties of silver and silver-copper lusters

Pradell

Pavlov

Gutiérrez

et al. 2012

Journal of Applied Physics

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Influence of alloy inhomogeneities on the determination by Raman scattering of composition and strain in Si1-xGex/Si(001) layers J. Appl. Phys. 112, 023512 (2012) Plasmon coupling in circular-hole dimers: From separation-to touching-coupling regimes J. Appl. Phys. 112, 013113 (2012) Correlation between reflectivity and resistivity in multi-component metallic systems Appl. Phys. Lett. 101, 011902 (2012) Ultrathin metallic coatings can induce quantum levitation between nanosurfaces Appl. Phys. Lett. 100, 253104 (2012) Transmittance and optical constants of Sr films in the 6-1220eV spectral range J. Appl. Phys. 111, 113533 (2012) Additional information on J. Appl. Phys. Lusters are composite thin layers of coinage metal nanoparticles in glass displaying peculiar optical properties and obtained by a process involving ionic exchange, diffusion, and crystallization. In particular, the origin of the high reflectance (golden-shine) shown by those layers has been subject of some discussion. It has been attributed to either the presence of larger particles, thinner multiple layers or higher volume fraction of nanoparticles. The object of this paper is to clarify this for which a set of laboratory designed lusters are analysed by Rutherford backscattering spectroscopy, transmission electron microscopy, x-ray diffraction, and ultraviolet-visible spectroscopy. Model calculations and numerical simulations using the finite difference time domain method were also performed to evaluate the optical properties. Finally, the correlation between synthesis conditions, nanostructure, and optical properties is obtained for these materials. V C 2012 American Institute of Physics. [http://dx

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Ion-Beam Archaeometry of Islamic Lustre Glazes

Cited by 6 publications

References 0 publications

Contemporary Golden‐Like Lusters on Ceramics: Morphological, Chemical, and Structural Properties

Contemporary Golden‐Like Lusters on Ceramics: Morphological, Chemical, and Structural Properties

Luster Pottery from the Thirteenth Century to the Sixteenth Century: A Nanostructured Thin Metallic Film

Composition, nanostructure, and optical properties of silver and silver-copper lusters

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