A trigger device and a triggered pseudospark switch (TPSS) were designed based on surface flashover technology, in order to meet the requirements from present pulse power technology and pulse current test technology such as a long lifetime, reliability in a wide voltage range, a short delay time, as well as small delay jitters. The trigger devices were made from different dielectric materials, with their permittivities from tens to thousands. The trigger characteristics of TPSS were investigated. The results indicate that the high-dielectric trigger device shows better performance and higher emitted charge of the electron emission within all adjusted parameters including the gas pressure and applied voltage. For the dielectric material with relative permittivity εr of 3460, when the gas pressure is 7 Pa, the hold-off voltage of TPSS is 28 kV, the minimum trigger switch voltage drops to 128 V, the minimum discharging delay time and delay jitter are less than 35ns and 6ns, respectively, and the reliable operation can be reached within a very large range of charging voltage, between 0.46% and 99% of its self-breakdown voltage.