Investigations of conducting polymers, carbon materials, oxide and sulfide materials for supercapacitor applications: a review

Kumar, Rajendra; Nagarani, S.; Sethuraman, Vijay A.; Andra, Swetha; Dhinakaran, V.

doi:10.1007/s11696-022-02124-0

Cited by 46 publications

(14 citation statements)

References 160 publications

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“…In contrast, pseudocapacitive electrode materials store charges via reversible surface/near-surface faradaic redox reactions and depict remarkable specic capacitances (>200 F g −1 ). 7 Adopting a pseudocapacitive electrode in SCs is a practical approach for constructing SCs with considerable energy densities (10-50 W h kg −1 ). Even though several conductive polymers (CPs) (i.e., polyaniline (PANI), polypyrrole (PPy), and poly (3,4-ethylenedioxythiophene) (PEDOT)) have been proven to be promising pseudocapacitive materials with high capacitance and excellent conductivity, 8 they are p-type doping CPs and usually performed as positive electrode materials in aqueous electrolyte devices.…”

Section: Introductionmentioning

confidence: 99%

“…In contrast, pseudocapacitive electrode materials store charges via reversible surface/near-surface faradaic redox reactions and depict remarkable specific capacitances (>200 F g −1 ). 7 Adopting a pseudocapacitive electrode in SCs is a practical approach for constructing SCs with considerable energy densities (10–50 W h kg −1 ). Even though several conductive polymers (CPs) ( i.e.…”

Section: Introductionmentioning

confidence: 99%

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Aromatic polyaroxydiazole pseudocapacitive anode materials with tunable electrochemical performance through side group engineering

Jiang,

Yang,

et al. 2024

J. Mater. Chem. A

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Aromatic polyaroxydiazole pseudocapacitive anode materials with tunable electrochemical performance through side group engineering

Jiang,

Yang,

et al. 2024

J. Mater. Chem. A

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“…Nickel oxide/high conductive carbon composites are promising electrode materials because of the high theoretical specific capacitance of NiO (2583 F g −1 ) [13]. However due to their inherently low conductivity (about 10 −4 S cm −1 ), NiO-based electrodes only reach a fraction of their theoretical capacitance [14,15].…”

Section: Introductionmentioning

confidence: 99%

Optimized 3D interconnected foam-like NiO@rGO composite as a binder-free electrode for high-performance asymmetric supercapacitor

Liu,

Shao,

Xue

et al. 2023

Mater. Res. Express

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Bonding of transition metal oxides and highly conductive carbon materials to exploit the synergistic effect of both materials has been proven to be an efficient means to develop high-capacity electrode materials. A unique interconnected foam-like NiO@rGO structure was constructed by loading the NiO nanoparticles onto rGO frameworks as a binder-free supercapacitor electrode via three steps including hydrothermal reaction, electrodeposition and heating treatment. The morphology and crystallinity were tuned by controlling the electrodeposition time and heating temperature, and the electrochemical properties of the NiO@rGO composites were systematically investigated. The optimized NiO@rGO-250 composite showed excellent electrochemical properties (1399 F g-1 at 1 A g-1) and superior cycling stability. Furthermore, an asymmetric supercapacitor using NiO@rGO and active carbon as two electrodes achieved a high specific energy of 40.4 Wh k g-1 at a specific power of 750 W k g-1.

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“…Porous carbon electrode, doped with different heteroatoms and even oxides, tends to be potential electrode material with high capacitance, and therefore improve the energy density of ES [ 1 , 2 , 3 ]. Various carbon precursors have been introduced in order to simplify the synthesis procedure of doped carbon materials.…”

Section: Introductionmentioning

confidence: 99%

“…In addition to this, DES found application in the synthesis of different nanomaterials and also in the synthesis of carbon materials. DES are the new generation of carbon precursors which satisfy most green chemistry principles in carbon material synthesis [ 1 , 14 ]. The use of DES offers one-step synthesis route for preparation of different heteroatom-doped carbon materials.…”

Section: Introductionmentioning

confidence: 99%

Deep Eutectic Solvent for Facile Synthesis of Mn3O4@N-Doped Carbon for Aqueous Multivalent-Based Supercapacitors: New Concept for Increasing Capacitance and Operating Voltage

et al. 2022

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The capacitance and operating voltage of supercapacitors as well as their energy density have been increased by development of different materials and electrolytes. In this paper, two strategies, for the first time, were used to improve energy density: Mn3O4- and N-dual doped carbon electrode and aqueous mixture of multivalent ions as electrolyte. Mn3O4- and N-dual doped carbon was prepared by a novel and cost-effective procedure using deep eutectic solvent. XRD, XPS, and FTIR confirmed presence of Mn3O4 and nitrogen, while SEM and EDS elemental mapping showed micrometer-sized nanosheets with uniform distribution of C, O, N, and Mn atoms. Charge storage behavior of carbon was tested in aqueous multivalent-based electrolytes and their mixture (Ca2+-Al3+). Regarding both specific capacitance and workable voltage, the Ca2+-Al3+ mixed electrolyte was found as the best optimal solution. The calcium addition to the Al-electrolyte allows the higher operating voltage than in the case of individual Al(NO3)3 electrolyte while the addition of Al3+ ion in the Ca(NO3)2 electrolyte improves the multivalent-ion charge storage ability of carbon. As a result, the specific energy density of two-electrode Mn3O4@N-doped carbon//Al(NO3)2+Ca(NO3)2//Mn3O4@N-doped carbon supercapacitor (34 Wh kg−1 at 0.1 A g−1) overpasses the reported values obtained for Mn-based carbon supercapacitors using conventional aqueous electrolytes.

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Investigations of conducting polymers, carbon materials, oxide and sulfide materials for supercapacitor applications: a review

Cited by 46 publications

References 160 publications

Aromatic polyaroxydiazole pseudocapacitive anode materials with tunable electrochemical performance through side group engineering

Aromatic polyaroxydiazole pseudocapacitive anode materials with tunable electrochemical performance through side group engineering

Optimized 3D interconnected foam-like NiO@rGO composite as a binder-free electrode for high-performance asymmetric supercapacitor

Deep Eutectic Solvent for Facile Synthesis of Mn3O4@N-Doped Carbon for Aqueous Multivalent-Based Supercapacitors: New Concept for Increasing Capacitance and Operating Voltage

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