Foaming
of oils often confronts researchers in food, cosmetics,
and petrochemical industries. Destabilization or stabilization of
nonaqueous foams is fundamentally crucial for process control and
product quality. Antifoams can be a useful method to control excessive
foams. Nonetheless, the foaming mechanisms and the selection criteria
of the most common antifoam, poly(dimethylsiloxane) (PDMS) oils, are
not thoroughly discussed. The study of inorganic colloidal particles
as foam stabilizers has drawn particular attention over the past years
practically and academically, yet only a small part of literature
focuses on nonaqueous foams. For these reasons, we have studied the
effects of PDMS oils and silica nanoparticles on the foaming of oils.
We find that the performance of silicone oils as crude oil antifoams
is firmly related to PDMS viscosity and crude oil composition presumably
because the solubilization of PDMS oils in hydrocarbons reduces with
increasing viscosity of the polymers and the hydrocarbons. The findings
also illustrate that nanoparticle hydrophobicity and concentration
are the primary factors for the foam stabilization effect.