Investigation of the tribological properties of Ti-TiN-(Ti,Al,Nb,Zr)N composite coating and its efficiency in increasing wear resistance of metal cutting tools

Grigoriev, S. N.; Vereschaka, Alexey; Milovich, Filipp; Migranov, Mars; Andreev, Nikolay; Bublikov, Jury; Sitnikov, Nikolay; Oganyan, Gaik

doi:10.1016/j.triboint.2021.107236

Cited by 28 publications

(16 citation statements)

References 66 publications

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“…The main parameters of the coating deposition process are presented in Table 2 The special technique and equipment developed in co-operation with USATU RAS-MSTU STANKIN [79][80][81][82] were used to study the tribological properties o The chemical composition of Ti-6Al-4V allow is described in Table 1. The coatings were deposited using an upgraded VIT-2 vacuum plasma unit [66][67][68][69][70], (IDTI RAS-MSTU STANKIN, Moscow, Russia).…”

Section: Methodsmentioning

confidence: 99%

Comparison of the Mechanical Properties and Corrosion Resistance of the Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN Coatings

Zhylinski

Vereschaka

et al. 2023

Coatings

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In this work, the mechanical properties and corrosion resistance of Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN coatings deposited by the physical vapor deposition (PVD) method on Ti-6Al-4V alloy were compared. The phase composition of the coatings, their hardness and fracture resistance in scratch tests were determined, and their structural characteristics were also studied using a scanning electron microscope (SEM) and a transmission electron microscope (TEM). The diffraction spectra were made using an automatic X-ray diffractometer. The value of the adhesive component of the friction coefficient fadh of the pair “coated and uncoated Ti-6Al-4V alloy” was investigated in the temperature range of 20–900 °C. The lowest value of fadh was detected for the Zr-ZrN coating at temperatures below 400 °C, while for the Mo-MoN coating it was observed at temperatures above 700 °C. The polarization curves of the coated and uncoated samples were performed in a 3% aqueous NaCl solution. The level of corrosion of the Ti-6Al-4V alloy samples with Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN coatings was evaluated using the Tafel extrapolation method, the iteration method, and the polarization resistance method. The results obtained with these methods indicate that the Zr-ZrN coated sample has the best corrosion resistance in the 3 wt.% NaCl solution, with a corrosion current density of 0.123 μA/cm2.

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Section: Methodsmentioning

confidence: 99%

Comparison of the Mechanical Properties and Corrosion Resistance of the Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN Coatings

Zhylinski

Vereschaka

et al. 2023

Coatings

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“…The composition of the coatings was determined based on an analysis of the studies available and earlier experimental results [53][54][55][56][57][58][59][60][61][62][63][64]. In particular, the content of molybdenum (Mo) and aluminum (Al) in all the coatings under consideration was 40 at.% and about 10 at.%, respectively.…”

Section: Methodsmentioning

confidence: 99%

“…Earlier papers considered the tribological properties of the described coatings [53,57,58] and the patterns of wear and fracture during the turning of 1045 steel using tools with the described coatings [57,[59][60][61]. The general pattern of wear on metal-cutting tools during the tuning of nickel alloys was also considered [62][63][64].…”

Section: Introductionmentioning

confidence: 99%

Investigation of the Nature of the Interaction of Me-MeN-(Me,Mo,Al)N Coatings (Where Me = Zr, Ti, or Cr) with a Contact Medium Based on the Ni-Cr System

et al. 2022

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This paper discusses the results of a study focused on the nature of the interaction of Me-MeN-(Me,Mo,Al)N coatings (where Me = zirconium (Zr), titanium (Ti), or chromium (Cr)) with a contact medium based on the Ni-Cr system. The studies were carried out during the turning of nickel–chromium alloy at different cutting speeds. The hardness of the coatings was found, and their nanostructure and phase composition were studied. The experiments were conducted using transmission electron microscopy (TEM), X-ray diffraction (XRD), and selected area electron diffraction (SAED). According to the studies, at elevated cutting speeds, the highest wear resistance is demonstrated by the tools with the ZrN-based coating, while at lower cutting speeds, the tools with the TiN- and CrN-based coatings had higher wear resistance. At elevated cutting speeds, the experiments detected the active formation of oxides in the ZrN-based coating and less active formation of oxides in the CrN-based coating. No formation of oxides was detected in the TiN-based coating. The patterns of cracking in the coatings were also studied.

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“…They suggested that the oxidation temperature of the coating was increased to 900 °C owing to the addition of Hf, which forms Hf-based oxynitrides and Al/Ti-based oxide layers during HT exposure. On the other hand, a study by Grigoriev et al [60] showed that Ti-TiN-(Ti, Al, Nb, and Zr)N multicomponent coatings significantly enhanced the wear resistance and reduced the friction and performance of cutting tools with increasing the temperature from 700 to 900 °C .…”

Section: Binary Ternary and Multicomponent Ceramic Coatingsmentioning

confidence: 99%

“…As a result, coatings with surface oxide layers can easily form smooth and dense adhesive layers, potentially reducing friction and wear [111]. Other remarkable functional coating concepts from recent studies to enhance tribological performance have been achieved by designing compositionally gradient coatings [109,[112][113][114], novel multilayer coatings [73,75,89,115,116], and nanocomposite coatings [60].…”

Section: Functionally Modified Coatingsmentioning

confidence: 99%

State-of-the-Art Developments in Advanced Hard Ceramic Coatings Using PVD Techniques for High-Temperature Tribological Applications

2023

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Hard and wear-resistant coatings created utilizing physical vapor deposition (PVD) techniques are extensively used in extreme tribological applications. The friction and wear behavior of coatings vary significantly with temperature, indicating that advanced coating concepts are essential for prolonged load-bearing applications. Many coating concepts have recently been explored in this area, including multicomponent, multilayer, gradient coatings; high entropy alloy (HEA) nitride; and functionally modified coatings. In this review, we highlighted the most significant findings from ongoing research to comprehend crucial coating properties and design aspects. To obtain enhanced tribological properties, the microstructure, composition, residual stress, hardness, and HT oxidation resistance are tuned through doping or addition of appropriate materials at an optimized level into the primary coatings. Such improvements are achieved by optimizing PVD process parameters such as input power, partial pressure, reactive gas flow rates, substrate bias, and temperature. The incorporation of ideal amounts of Si, Cr, Mo, W, Ag, and Cu into ternary and quaternary coatings, as well as unique multilayer designs, considerably increases the tribological performance of the coatings. Recent discoveries show that not only mechanical hardness and fracture toughness govern wear resistance, but also that oxidation at HT plays a significant role in the lubrication or wear failure of coatings. The tribo-induced metal oxides and/or Magnéli phases concentrated in the tribolayer are the key governing factors of friction and wear behavior at high temperatures. This review includes detailed insights into the advancements in wear resistance as well as various failure mechanisms associated with temperature changes.

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Investigation of the tribological properties of Ti-TiN-(Ti,Al,Nb,Zr)N composite coating and its efficiency in increasing wear resistance of metal cutting tools

Cited by 28 publications

References 66 publications

Comparison of the Mechanical Properties and Corrosion Resistance of the Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN Coatings

Comparison of the Mechanical Properties and Corrosion Resistance of the Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN Coatings

Investigation of the Nature of the Interaction of Me-MeN-(Me,Mo,Al)N Coatings (Where Me = Zr, Ti, or Cr) with a Contact Medium Based on the Ni-Cr System

State-of-the-Art Developments in Advanced Hard Ceramic Coatings Using PVD Techniques for High-Temperature Tribological Applications

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