Abstract:Based on first‐principles with the generalized gradient approximation (GGA) of the Perdew–Burke–Ernzerhof (PBE) form, the authors carry out systematic investigations regarding the electronic structures and optical properties of zinc‐blende (ZB) ZnS doped with six types of transition metals. The Cd‐doped system has greater structural stability with a lower formation energy of 0.526 eV compared to other systems. Additionally, the band structures of systems are employed to show the superior semiconductor capacity… Show more
“…4a), in agreement with the literature. 32 In comparison, the VBM of Cd/ZnS is constituted by S 3p, Zn 3d, and Cd 4d orbitals, with dominant contributions from Cd 4d (Fig. 4b).…”
C−O bond scission via photocatalysis is an important step in biomass depolymerization. Here, we demonstrate the scission of strong ether C−O bonds promoted by low-work-function Cd single atoms and clusters....
“…4a), in agreement with the literature. 32 In comparison, the VBM of Cd/ZnS is constituted by S 3p, Zn 3d, and Cd 4d orbitals, with dominant contributions from Cd 4d (Fig. 4b).…”
C−O bond scission via photocatalysis is an important step in biomass depolymerization. Here, we demonstrate the scission of strong ether C−O bonds promoted by low-work-function Cd single atoms and clusters....
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