Investigation of the electrocatalytic reaction for the oxidation of alcohols through the formation of a metal organic framework (Mn-MIL-100)/polymer matrix on the surface of an Au electrode

Abstract

An electrode composite containing a metal organic framework (Mn-MIL-100) was prepared by linkers including gold nanoparticles/polypyrrole and cysteine.

Modification of Glassy Carbon Electrodes with Complexes of Manganese(II) with Some Phenanthroline Derivatives Immobilized in Nafion Layer

“…For this reason, interest in the synthesis of Mn ion complexes to study their structural, chemical, electrochemical and oxidative properties has developed and continues to grow [5][6][7]. However, the problems of separating the catalyst from the reaction products and regenerating its active form are causing research to shift from homogeneous catalysis toward heterogeneous catalysis and electrocatalysis [8][9][10][11][12][13][14]. Catalysts are immobilized in inorganic materials [10] and in polymers [11,12].…”

A sustainable protocol for selective alcohols oxidation using a novel iron-based metal organic framework (MOF-BASU1)

“…Recently, various homogeneous catalysts have played an important role owing to their efficiency and all-purpose impact on the many catalytic reactions. 7–9 However, despite the high efficiency of homogeneous catalysts, all these reactions suffer from poor catalyst recovery. The benefits of catalyst recovery include the economic and environmentally friendly concept of special transition metals; however, the key challenges are yet to be resolved.…”

Pd nanoparticles decorated on a porous Co(BDC-NH2) MOF as an effective heterogeneous catalyst for dye reduction

“…1 Nowadays, MOFs are considered to be good candidates for synthesizing supported catalysts, as science and technology today emphasize using sustainable processes and materials. 2–4…”

“…1 Nowadays, MOFs are considered to be good candidates for synthesizing supported catalysts, as science and technology today emphasize using sustainable processes and materials. [2][3][4] Numerous studies have demonstrated the catalytic application and synthesis of different MOF derivatives with postimmobilized metal ions, pre-modied ligands, and metal nanoparticles (NPs). Several post-synthetic modication (PSM) methods have been described for functionalizing the organic carriers and secondary building units (SBUs) of MOFs.…”