Investigation of the effect of heat treatment on the inductive effect of GO membrane during the ion diffusion process

Abstract

The inductive effect of 2D material in an aqueous solution can be potentially applied in biological implantable electronic devices. In this paper, graphene oxide (GO) membranes were prepared via the vacuum filtration method and then treated under different heat temperatures. X-ray diffraction and scanning electron microscopy results showed the shrinkage of the interlayer spacing in the GO membrane, while Fourier transform infrared results indicated the loss of oxygen-containing polar groups during the heat treatment. EIS results confirmed the inductive signal of the GO membrane appeared during the ion diffusion process. And the inductive effect can be controlled by the polar groups and the interlayer spacing in the GO membrane. Moreover, at lower electrolyte concentrations (0.0100 mol/L), more polar groups lead to a stronger inductive signal, while at higher electrolyte concentrations (0.10 mol/L), narrower interlayer spacing results in a stronger inductive signal. The investigation may provide a key clue to tune the inductance of the biological electronic device based on GO.

Study of Ions Transport Behavior of Heat-Treated MXene Membranes

“…A reduction of intensity with the increasing heating temperature in the XRD pattern can be found. This is because the location of the reduction in the interlayer spacing during the heat treatment is random. , Therefore, higher heating temperatures lead to lower diffraction peak intensities, which is in agreement with previous studies. − It can be seen that as the heating temperature increased, the peak apex of the 2θ angle assigned to the (002) ,, crystal face shifted slightly to higher angles, which was located at 7.1, 7.5, and 7.8°. According to Bragg’s law (eq ), the width of nanochannels of the membrane decreased with the increasing heating temperature, which could be attributed to the self-cross-linking and dehydration of the adjacent MXene sheets.…”