“…The σ-profile is partitioned into three primary regions: the hydrogen bond donor region (σ < −0.0082 e Å −2 ), represented by the blue sigma surface; the non-polar region (−0.0082 < σ < +0.0082 e Å −2 ), corresponding to the green sigma surface; and the hydrogen bond acceptor region (σ > +0.0082 e Å −2 ), depicted by the red sigma surface. 33,34 As depicted in Fig. 4, the σ-profile of C 3 F 6 is mostly distributed in the non-polar region, and only a small part is distributed in the hydrogen bond donor region (blue σ-surface).…”