Investigation of regularities of pelletized biomass thermal deformations during pyrolysis

Abstract

Gasification process is a fairly complicated matter and using pelletized biomass for the gasification mostly results in fuel agglomeration. The pelletized biomass moving from the pyrolysis zone to the oxidation zone sticks together in lumps and disrupts entire process. In order to determine the regularities of thermal deformations, experimental research of pelletized biomass thermal deformations during pyrolysis were performed in a horizontal pyrolysis reactor from 300-900 °C temperature capturing wood particle, wheat straw and wood pellet radial changes by a digital camera. Also the center temperature and the mass loss of samples were measured to determine cause of biomass thermal deformations. Observed results reveal that when increasing the pyrolysis temperature from 400-900 °C, the wheat straw and wood pellets expand at the beginning of pyrolysis process and after it start to shrink, while wood particle is only affected by shrinkage. The swelling effect of pelletized samples starts decreasing over 600-650 °C heating temperature and disappears when the temperature is higher than 850 °C. Biomass shrinkage intensifies exponentially as the heating temperature increases till 700-750 °C. However, the final shrinkage starts to decrease as the heating temperature increases from 700-750 to 900 °C due to swelling of formed char. Determined phenomenon of pelletized biomass swelling explains cause of fuel adhesion in pyrolysis zone of gasifier. Besides estimated regularities of biomass thermal deformations upon pyrolysis could be used to improve the existing numerical models of biomass pyrolysis.

Oxidative pyrolysis of pine wood, wheat straw and miscanthus pellets in a fixed bed

“…The reduction in particle diameter was then calculated be 28%, 24% and 21%. These values are in line with several studies focused on particle shrinkage of pelletized biomass during pyrolysis, with a temperature range of 300-800°C [24,25].…”

Characterizing devolatilized wood pellets for fluidized bed applications

“…Related to the properties during and after thermo-chemical conversion only some aspects can already be found in the literature. Paulauskas et al [16] studied shrinkage and swelling during pyrolysis of wood pellets. Strandberg et al [28] showed with computed tomography images the generation of cavities during devolatilization and the change in the structure during combustion.…”

Modification of Biochar Formation during Slow Pyrolysis in the Presence of Alkali Metal Carbonate Additives

“…Acting catalytically, chemical addition can affect char-forming and cross-linking reactions and results in a more solid sample residue. On the basis of past studies in coal slow pyrolysis, ,, in contrast with the diluent role of SiO 2 , Ca compounds have catalytic roles in pyrolysis.…”

“…Although most swelling publications are related to coal materials 49,50,53,55 and few available investigations in biomass, 56−58 particularly in biomass devolatization, 46,54 the results of the present work are comparable to coal-based behaviors. Pyrolysis of biomass in the vicinity with the eutectic generates bubbles, particularly for particles near the additive salt (Figures 3 and 4).…”