Background: The density-dependent nuclear symmetry energy is directly related to the isospin asymmetry for finite and infinite nuclear systems. It is critical to determine the coefficients of symmetry energy and its related observables as it holds great importance in different areas of nuclear physics, such as analyzing the structure of ground state exotic nuclei and neutron star study. Purpose: The ground state bulk properties such as nuclear binding energy (B.E.), quadrupole deformation (β2), two-neutron separation energy (S2n), the differential variation of two-neutron separation energy (dS2n), and root-mean-square charge radius (r ch ) for Scandium (Z = 21), and Titanium (Z = 22) nuclei are calculated. The isospin properties, namely the coefficient of nuclear symmetry energy and its components such as surface and volume symmetry energy for the finite isotopic chain from the corresponding quantities of infinite nuclear matter, are also estimated. Finally, we correlate the neutron-skin thickness with the coefficient of symmetry energy and its related observables corresponding to these isotopic chains of nuclei. Methods: The coherent density fluctuation model (CDFM) is used to estimate the isospindependent properties of finite nuclei such as symmetry energy, surface symmetry energy, and volume symmetry energy from its corresponding component in infinite nuclear matter. The relativistic mean-field (RMF) formalism with non-linear NL3 and Relativistic-Hartree-Bogoliubov with densitydependent DD-ME2 interaction parameters are employed in the present analysis. The weight function |F(x)| 2 is estimated using the total density of each nucleus, which in turn is used along with the nuclear matter quantities to obtain the effective symmetry energy and its components in the finite nuclei. Results: We calculate the ground state bulk properties such as nuclear binding energy, quadrupole deformation, two-neutron separation energy, the differential variation of two-neutron separation energy, and root-mean-square charge radius for the Sc-and Ti-isotopic chains based on non-linear NL3 and density-dependent DD-ME2 parameter sets. Further, the ground state density distributions are used within the CDFM to obtain the effective surface properties such as symmetry energy and its components, namely volume and surface symmetry energy, for both the parameter sets. The calculated quantities are used to understand the isospin dependent structural properties of finite nuclei near and beyond the drip line that will further our horizon of finding newer magicity along the isotopic chains. Conclusions: A shape transition is observed from spherical to prolate near N ≥ 44, and N ≥ 40 for Sc-and Ti-isotopic chain, respectively. Notable signatures of shell and/or sub-shell closures have been found for the magic neutron numbers at N = 20 and 28 for both the isotopic chain using the nuclear bulk and isospin quantities. In addition to these, a few signatures of shell/sub-shell closure are observed near drip-line region, at N = 34 and 50 by following ...