Investigation of photochromic cluster systems based on molybdenum oxides by ESR spectroscopy

Synthesis, structure and photochromic properties of a novel 1,6-hexanediamine trimolybdate supramolecular compound

“…6 indicate that the as-synthesized sample exhibits no ESR signals, while the irradiated samples exhibit characteristic ESR signals of Mo (V) atoms [11,[20][21][22]. It can be concluded from this that Mo (VI) atoms are reduced to Mo (V) atoms after the assynthesized samples were irradiated by UV light.…”

Formation of photoelectron spectra of alloys niobium-molybdenum-zirconium

“…The C peak at 1.2-1.3 eV is most likely associated with the density of electronic states of hafnium since the position of this maximum did not change after the photoelectron spectra were taken at hν = 10 eV. We associate peaks A and C with indirect optical transitions [13,14] for a pure Mo (111) single crystal. Thus, the photoelectron spectra for pure Mo (111) exhibit maxima due to the band structure of molybdenum, and in the spectrum obtained after doping with zirconium ions, an additional maximum appears at 1.2-1.3 eV below the Fermi level [15][16][17][18][19][20].…”

Thermal transformations in In-MoO3 nanofilms

“…Studies of heterogeneous nanosystems are of technological importance and can be useful in gaining insight into the mechanism of solid state transformations [3][4][5][6][7]11]. Indium, molybde num(VI) oxide, and related materials are widely used in scientific, technological, and industrial applications owing to their advantageous properties and, as a conse quence, have attracted considerable attention of researchers in various fields [1][2][3][4][8][9][10][11][12][13][14][15][16][17][18][19][20][21].…”