Investigation of optical, thermal and mechanical studies on semi organic nonlinear optical diaquabis(L-lactato)magnesium (DLLM) single crystal for optoelectronic devices applications

Raja, R.; Samuel, R. Sugaraj; Chithambaram, V.; Viju, G.; Janarthanan, S.; Hidayathullah, A. Mohamed

doi:10.1007/s10854-022-08821-6

Cited by 7 publications

(3 citation statements)

References 52 publications

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“…Optical characteristics are crucial for a material because they make available the details on its electronic band structures, its localized states and also its types of optical transitions [16]. The optical band gap is a crucial factor for the NLO applications involving lasers and waveguides.…”

Section: Optical Absorption Analysismentioning

confidence: 99%

Investigations on synthesis, growth and characterisations of a NLO material: L-Tryptophanium phosphite (LTP)

Santhi,

Samuel,

Raja

et al. 2024

JOR

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The nonlinear optical material L-Tryptophanium phosphite (LTP) was synthesised and grown by the process of slow evaporation solution growth. Characterisations like single crystal XRD, FT-IR, and H1 NMR spectral measurements were done to find the crystal structure and functional groups. The crystal was found to possess good transparency for the whole visible region from the UV-Vis-NIR spectral analysis. The thermal behaviour like stability and breakdown of the crystal were assessed using TG-DTA analyses. The hardness of the crystal was determined using Vickers micro hardness study. The KurtzPerry approach was used to study the nonlinear optical (NLO) characteristics of the crystal. A good value of conversion efficiency in second harmonic generation (SHG) makes the generated crystal suitable for frequency conversion.

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Section: Optical Absorption Analysismentioning

confidence: 99%

Investigations on synthesis, growth and characterisations of a NLO material: L-Tryptophanium phosphite (LTP)

Santhi,

Samuel,

Raja

et al. 2024

JOR

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“…Organic molecular materials with a high degree of delocalized electrons have received a great deal of attention due to the compound's additional supporting nonlinear response [12]. Amino acids are attractive materials in the field of nonlinear optics because they have higher SHG efficiency than conventional KDP [13,14]. Thus, the curiosity of researchers is focused on amino acids, which have a group of hydrogen-bonded nature that show very good NLO properties [15,16].…”

Section: Introductionmentioning

confidence: 99%

Investigations on the synthesis and growth and structural, spectral, optical, mechanical and thermal properties of non-linear optical single crystals of Bis-L-Seriniumoxalate Dihydrate (BLSOD)

Hidayathullah¹,

Samuel²,

Chithambaram³

et al. 2023

JOR

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From the raw materials L-Serine and oxalic acid, the product Bis-LSeriniumoxalatedehydrate(BLSOD) was created. By using a slow evaporation process, the individual BLSOD crystals were produced from aqueous solution. According to single crystal X-ray Diffraction investigations, the structure of the produced crystal is monoclinic. The existence of different functional groups and the chemical environment present in the synthesised material were qualitatively determined through the use of Fourier Transform Infra-Red (FTIR) and proton nuclear magnetic resonance (H1NMR) spectrum studies. The crystal's transparency in the visible and near-infra-red areas was confirmed by UV-Visible-Near infrared and photoluminescence spectrum tests, which also looked at the material's viability for device construction. To determine the crystal's machinability, the mechanical properties of the material were carefully examined using Vicker's hardness research. Thermal investigations such as Thermo gravimetric (TGA) and Differential thermal analysis (DTA) have shown the thermal stability of BLSOD and the phases of weight losses. As a function of frequency and temperature, the dielectric constant and dielectric loss of grown crystals were determined. The Kurtz-Perry powder test was used to check both the second harmonic generation (SHG) and then the NLO property of the material.

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“…Thiosemicarbazide (TSC) and its derived compounds are of tremendous interest in scienti c and technological progress due to their unique structural, chemical, and biological activities [9]. The thiosemicarbazide molecule is centrosymmetric by nature, but when combined with inorganic compounds, complexes are produced that are noncentrosymmetric [10,11]. In this study, potassium bromide is attached to thiosemicarbazide to generate a novel semi organic (metal-organic) compound in this series [12][13][14][15].…”

Section: Introductionmentioning

confidence: 99%

Investigation of optical, Thermal studies on semi organic Nonlinear Optical Single Crystal Thiosemicarbazide Potassium Bromide (TSCPB) for Optoelectronic devices applications

Rajeshwari

Raja²,

Saravanan³

et al. 2023

Preprint

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The Thiosemicarbazide Potassium Bromide (TSCPB) single crystals have been grown by the slow evaporation solution growth technique. The lattice parameters and crystalline nature of the grown TSCPB crystals have been studied by single XRD analysis. The chemical composition and the corresponding functional groups of the grown TSCPB have been confirmed by FTIR studies. The optical transparency of TSCPB in the visible region has been confirmed by the UV-Vis-NIR spectrum, and it has also been ensured by the maximum wavelength emission from the photoluminescence study. The band gap of the TSCPB material was calculated from optical absorption studies. The DSC analysis ascertained the thermal stability of the material. The morphology of the grown TSCPB crystal was studied. The second harmonic generation of TSCPB crystal has been determined by the standard Kurtz and Perry powder method.

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Investigation of optical, thermal and mechanical studies on semi organic nonlinear optical diaquabis(L-lactato)magnesium (DLLM) single crystal for optoelectronic devices applications

Cited by 7 publications

References 52 publications

Investigations on synthesis, growth and characterisations of a NLO material: L-Tryptophanium phosphite (LTP)

Investigations on synthesis, growth and characterisations of a NLO material: L-Tryptophanium phosphite (LTP)

Investigations on the synthesis and growth and structural, spectral, optical, mechanical and thermal properties of non-linear optical single crystals of Bis-L-Seriniumoxalate Dihydrate (BLSOD)

Investigation of optical, Thermal studies on semi organic Nonlinear Optical Single Crystal Thiosemicarbazide Potassium Bromide (TSCPB) for Optoelectronic devices applications

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