Using technique of computerized signal-averaging of photocurrent transient, we have studied the details of deep 1evel states in high resistivity ZnSe crystals. The time resolved spectra of photocurrent and four-gate P1CT spectra are presented.PACS numbers: 72.20.Jv, 72.40.+w Detailed investigations of photoconductivity in II-VI semiconductors have been concentrated mainly on CdS and CdSe single crystals and powders but only few [1][2][3] on the mechanism of photo conductivity of ZnSe single crystals. The electrical and optical properties of these compounds are often affected by the presence of some dopants or native defects which are easily introduced during the high temperature growth and sample preparation processes. In general in these compounds the photocurrent transients are non-exponential because of a non-linear multi channel recombination mechanisms. The presence of two or more deep traps with nearly equal thermal activation energies could lead to a signal comprised of two or more exponentials, one faster than the other. In order to determine the nature of the traps one has to know whether the transient current is due to electrons or holes.In this work we have made photo-induced current transient measurements on the high resistivity ZnSe crystals. The ZnSe crystals were grown by the high pressure Bridgman method using Koch Light ZnSe powder as a source material. TheThis work was supported in part by CPBP 01.06.(295)