An extrinsic optical fibre temperature sensor has been investigated and results are presented. A coating consists of a combination of two inorganic phosphors. Thermal quenching dominates the luminescent characteristics of one phosphor at temperatures in the range of interest while the other more stable phosphor is used as a reference. Ratios of their peak emission intensities are calculated and analysed. The phosphor mixture is coated onto a Pyrex beaker. Boiling water is poured into beaker and the ratio is calculated as the temperature of the water decreases from 8OC to 3OC. Results show an increasing ratio for decreasing temperature. This paper describes the testing of the coating and its application, as part of a temperature sensor, for monitoring surface temperatures in electromagnetically harsh industrial environments.