Investigating the properties and biological activity of a new Cu(II) complex with a 2-Dimethyaminopyridinium cation (C7H12N2)2[CuCl4]

Alotaibi, Abdullah A.

doi:10.1016/j.jksus.2023.102620

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2024

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Cited by 3 publications

References 44 publications

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Preparation, Crystal Structure, Optical Properties, Hirshfeld Surface Analysis and Antibacterial Activity of 4-Nitrobenzyl-4-aminopyridinium Tetrachlorocuprate(II)

Li,

Huang,

et al. 2024

J Chem Crystallogr

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Preparation, Crystal Structure, Optical Properties, Hirshfeld Surface Analysis and Antibacterial Activity of 4-Nitrobenzyl-4-aminopyridinium Tetrachlorocuprate(II)

Li,

Huang,

et al. 2024

J Chem Crystallogr

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Characterization of a New Hybrid Perovskite Material for Renewable Energy (C7H11N2)2[FeCl4]: Synthesis, IR Spectroscopy, and Optical Properties

Alotaibi

2024

Arab J Sci Eng

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Preparation, crystal structure, optical properties, Hirshfeld surface analysis and antimicrobial activity of 4-nitrobenzyl-4-aminopyridinium tetrachlorocuprate(II)

Li,

Huang,

et al. 2024

Preprint

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In this study, we have synthesized a novel organic-inorganic hybrid crystal 4-nitrobenzyl-4-aminopyridinium tetrachlorocuprate(II) [4NO2Bz-4NH2Py]2[CuCl4](1). The single-crystal X-ray diffraction analysis revealed that the crystal belongs to the triclinic space group P–1, and consists of four [4NO2Bz-4NH2Py]+ cations and two [CuCl4]2– anions. O···π, C–H∙∙∙π, π∙∙∙π, N–H∙∙∙Cl, C–H∙∙∙Cl, C–H∙∙∙O, and C–H∙∙∙N weak interactions in the crystals play an important role in facilitating the stacking and stabilization of the crystals. The different types of contribution have been quantified by the calculation of Hirschfeld surface percentage and depicted by fingerprint plots. The bulk phase purity, homogeneity, and morphology of the desired compound were checked using powder XRD, and SEM-EDX analysis. Vibrational, optical, and thermal properties were investigated by FT-IR, UV-Vis spectrum, and TG-DTA measurements of [4NO2Bz-4NH2Py]2[CuCl4](1), respectively. The low energy gap (2.41 eV) suggested that the crystal was a suitable semiconductor material for optical applications. In addition, the compound presented good bactericidal activity against E. coli and S. aureus.

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Investigating the properties and biological activity of a new Cu(II) complex with a 2-Dimethyaminopyridinium cation (C7H12N2)2[CuCl4]

Cited by 3 publications

References 44 publications

Preparation, Crystal Structure, Optical Properties, Hirshfeld Surface Analysis and Antibacterial Activity of 4-Nitrobenzyl-4-aminopyridinium Tetrachlorocuprate(II)

Preparation, Crystal Structure, Optical Properties, Hirshfeld Surface Analysis and Antibacterial Activity of 4-Nitrobenzyl-4-aminopyridinium Tetrachlorocuprate(II)

Characterization of a New Hybrid Perovskite Material for Renewable Energy (C7H11N2)2[FeCl4]: Synthesis, IR Spectroscopy, and Optical Properties

Preparation, crystal structure, optical properties, Hirshfeld surface analysis and antimicrobial activity of 4-nitrobenzyl-4-aminopyridinium tetrachlorocuprate(II)

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