“…A number of micromechanical and computational models, ranging from atomistic to continuum, have been put forth (cf., e. g., Leonov and Brown (1991); Krupenkin and Fredrickson (1999a,b); Tijssens et al (2000a,b); Estevez et al (2000a,b); Baljon and Robbins (2001); Socrate et al (2001); Drozdov (2001); Tijssens and van der Giessen (2002); Robbins (2003, 2004); Basu et al (2005); Saad-Gouider et al (2006); Zairi et al (2008); Seelig and Van der Giessen (2009) ;Reina et al (2013)), including consideration of nucleation and growth Figure 2: Crazing process in a steel/polyurea/steel sandwich specimen under opening mode fracture (Yong et al, 2009). of voids, craze nucleation, network hardening and disentanglement, chain strength, surface energy and other, that account, to varying degrees, for the observational evidence and relate macroscopic properties to material structure and behavior at the microscale. In parallel a large mathematical literature has evolved, discussing the possibility of cavitation in local models and possible nonlocal extensions which may ensure existence of minimizers, see for example Ball (1982); James and Spector (1991); Müller and Spector (1995); Conti and DeLellis (2003); Henao and Mora-Corral (2010). These advances notwithstanding, the connection between micromechanical properties and polymer fracture, and specifically any scaling laws thereof, has defied rigorous analytical treatment and characterization.…”