2014
DOI: 10.1002/anie.201308959
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Inverse Opal Spheres Based on Polyionic Liquids as Functional Microspheres with Tunable Optical Properties and Molecular Recognition Capabilities

Abstract: Based on the combination of the unique features of both polyionic liquids and spherical colloidal crystals, a new class of inverse opaline spheres with a series of distinct properties was fabricated. It was found that such photonic spheres could not only be used as stimuli-responsive photonic microgels, but also serve as multifunctional microspheres that mimic the main characteristics of conventional molecules, including intrinsic optical properties, specific molecular recognition, reactivity and derivatizatio… Show more

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Cited by 122 publications
(82 citation statements)
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“…The colorimetric response of CBPM sensors based on soft stimuli-responsive materials can originate from changes in both the periodicity and the refractive indices of its constituents, as shown in Figure 17C. Examples of soft materials used for CBPM sensors include hydrogels, 178 [287][288][289] and metal-organic frameworks. 290,291 Stimuli-induced shifts in the periodicity of these types of CBPM sensors can be induced by swelling or deformation that in turn results in the shift in the photonic stopband ( Figure 16B,i) and can be detected visually or using a spectrometer.…”
Section: Factors Influencing Sensing Applicationsmentioning
confidence: 99%
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“…The colorimetric response of CBPM sensors based on soft stimuli-responsive materials can originate from changes in both the periodicity and the refractive indices of its constituents, as shown in Figure 17C. Examples of soft materials used for CBPM sensors include hydrogels, 178 [287][288][289] and metal-organic frameworks. 290,291 Stimuli-induced shifts in the periodicity of these types of CBPM sensors can be induced by swelling or deformation that in turn results in the shift in the photonic stopband ( Figure 16B,i) and can be detected visually or using a spectrometer.…”
Section: Factors Influencing Sensing Applicationsmentioning
confidence: 99%
“…In addition to multiple analyte sensing, hierarchy can be achieved using superparticles, which have been used as dispersible indicators for various stimuli. For example, spherical inverse opal superparticles based on poly(ionic liquids) were used for recognition of various ions and solvents, 288,289 and protein-modified silica superparticles were used as coding carriers in multiplex immunoassays. 325 Additionally, the high surface area of the pores can be used for adsorption and triggered release of drugs in addition to sensing.…”
Section: Factors Influencing Sensing Applicationsmentioning
confidence: 99%
“…Particularly, polymer colloidal PCs have demonstrated important applications ranging from photonic papers [8], full-color displays [9] and UV protection [10], to responsive optic devices. Various fabrication methods for colloidal PCs have been developed to meet practical application requirements [11][12][13]. Self-assembly is a facile approach for the fabrication of colloidal PCs with stopband at UV and visible ranges [14], and could be easily modified for widespread manufacturing purposes.…”
Section: Introductionmentioning
confidence: 99%
“…After contact printing the anion or solution as chemical "ink", the shifted optical signal of the PIL-IOMS was obtained for principal component analysis. [ 95 ] Aizenberg et al developed a method for patterning multiple chemical functionalities on inverse opal PCs by repeated exposing the fi lm to oxygen plasma and different alkylchlorosilane vapors with masks. [ 96 ] Due to the different area-specifi c wetting properties, the fi lm displayed distinct optical patterns when immersed in the common solvents, which results in a special solvent-analysis chip.…”
Section: Photolithography For Sensing Arraysmentioning
confidence: 99%