Excited states in 14 O have been investigated both experimentally and theoretically. Experimentally, these states were produced via neutron-knockout reactions with a fast 15 O beam and the invariant-mass technique was employed to isolate the 1p and 2p decay channels and determine their branching ratios. The spectrum of excited states was also calculated with the Shell Model Embedded in the Continuum that treats bound and scattering states in a unified model. By comparing energies, widths and decay branching patterns, spin and parity assignments for all experimentally observed levels below 8 MeV are made. This includes the location of the second 2 + state that we find is in near degeneracy with the third 0 + state. An interesting case of sequential 2p decay through a pair of degenerate 13 N excited states with opposite parities was found where the interference between the two sequential decay pathways produces an unusual relative-angle distribution between the emitted protons.