Invariant expressions for linear complex mechanisms: Single-step substance case

Branco, Daniel; Yablonsky, Grigoriy; Marin, Guy; Constales, Denis

doi:10.1016/j.ces.2020.115587

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Kinetico-thermodynamic Invariants For Linear Complex Mech1

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2020

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“…The invariant expression can be determined for whichever single-step substances within a linear complex mechanism. The value of the invariant expression will be a generalization of the last equation in Equation (6) [ 16 ].…”

Section: Kinetico-thermodynamic Invariants For Linear Complex Mechmentioning

confidence: 99%

New Invariant Expressions in Chemical Kinetics

Yablonsky

Branco

Marin

et al. 2020

Entropy

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This paper presents a review of our original results obtained during the last decade. These results have been found theoretically for classical mass-action-law models of chemical kinetics and justified experimentally. In contrast with the traditional invariances, they relate to a special battery of kinetic experiments, not a single experiment. Two types of invariances are distinguished and described in detail: thermodynamic invariants, i.e., special combinations of kinetic dependences that yield the equilibrium constants, or simple functions of the equilibrium constants; and “mixed” kinetico-thermodynamic invariances, functions both of equilibrium constants and non-thermodynamic ratios of kinetic coefficients.

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Section: Kinetico-thermodynamic Invariants For Linear Complex Mechmentioning

confidence: 99%