The already detailed study of 107 Tc nucleus was complemented by a search for microsecond isomers at very low energy. For this purpose, this neutron-rich nucleus was produced by thermal-neutron-induced fission of 241 Pu. We have found a new 30.1 keV microsecond isomeric state which deexcites to the ground state by a strongly-hindered E1 transition. This isomer was identified as the 3/2 + level of the 1/2 + [431] intruder band in 107 Tc and is also the lowest-lying member of the band. The very low energy of the band head suggests a large quadrupole deformation. From a comparison with 105 Tc, where more information is known about the intruder band, it is deduced that the 1/2 + [431] band has a quadrupole deformation, 2 0.35 and a possible triaxial shape, γ ≈ 20 • .